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Herein, a non\u2010covalent approach is used to fabricate a series of bulk glasses exhibiting strong fluorescence from non\u2010aromatic amino acids (\u029f\u2010arginine, \u029f\u2010lysine, \u029f\u2010proline, and \u029f\u2010histidine) by co\u2010assembling them with tetrafluorophthalic acid (\n                    <jats:bold>FA<\/jats:bold>\n                    ).\n                    <jats:bold>FA<\/jats:bold>\n                    , amino acids, and non\u2010covalent bonding between them play essential roles in both glass formation and fluorescent properties. The high viscosity and rapid annealing process of the glass formation process effectively prevent the crystallization and packing of\n                    <jats:bold>FA<\/jats:bold>\n                    and amino acids, slow the free internal rotations of the amino acids, and reduce the intermolecular collisions, thus increasing the fluorescence emissions of glasses.\n                    <jats:bold>FA<\/jats:bold>\n                    \u2010amino acids glasses display high fluorescence quantum yields (&gt; 44%) and large Stokes shifts. Their fluorescence performance is maintained even under various harsh conditions, including low temperatures, exposure to organic solvents, and coating with porous materials. Based on their robust anti\u2010freezing adhesion capacity (4.77 MPa at \u221240\u00b0C, 3.30 MPa at \u2212196\u00b0C) and long\u2010term stable solid\u2010state luminescence characteristics, these materials show great potential as fluorescent coatings and labeling agents suitable for use at low temperatures.\n                  <\/jats:p>","DOI":"10.1002\/adma.202517671","type":"journal-article","created":{"date-parts":[[2025,12,27]],"date-time":"2025-12-27T07:02:27Z","timestamp":1766818947000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Metal\u2010Free Nanoarchitectonics of Fluorescent Transparent Materials via Co\u2010Assembling Non\u2010Aromatic Amino Acids and Tetrafluorophthalic Acid for Adhesion, Coating, and Information Encryption Applications"],"prefix":"10.1002","volume":"38","author":[{"given":"Guohong","family":"Yao","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical 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