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Herein, a metal\u2010adaptive SEI reconstruction strategy is proposed to leverage the reactivity\u2010guided diisopropoxy\u2010bisethylacetoacetatotitanate (DPBT) coatings on alkali metal anodes (TC\u2010Li\/TC\u2010Na). The resulting interphases both share a hierarchical architecture with an ultrathin titanate layer and a TiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based inner matrix connected through compositionally graded segments (Ti\u2013O\u2013M, M = Li\/Na\/C), yet demonstrate metal\u2010specific structural differentiation. The moderate reactivity of Li facilitates the dense packing of larger TiO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles, forming a low\u2010porosity, high\u2010modulus layer that mechanically suppresses dendrites. Conversely, the more rapid reaction of Na instantly produces abundant gas bubbles and fosters a highly porous network with interconnected ultrasmall TiO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles, integrating moderate modulus with elevated surface roughness that dynamically accommodates volumetric strain and enhances interfacial activity. Consequently, the NCM811||TC\u2010Li pouch cell achieves high\u2010capacity retention (89.3%, 200 cycles, 456.8\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) under 0.2 C\/0.5 C and stable operation under high capacity and high energy density of 11.1 Ah and 550.2\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    , while NFM||TC\u2010Na pouch cell deliveries exceptional cycling stability at 0.3 C\/1 C (79.7% retention over 200 cycles).\n                  <\/jats:p>","DOI":"10.1002\/adma.202518151","type":"journal-article","created":{"date-parts":[[2025,11,20]],"date-time":"2025-11-20T06:43:03Z","timestamp":1763620983000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Reactivity\u2010Driven Metal\u2010Adaptive Interphases for Dendrite\u2010Free, High\u2010Rate Alkali Metal Anodes"],"prefix":"10.1002","volume":"38","author":[{"given":"Jialin","family":"Lin","sequence":"first","affiliation":[{"name":"National Engineering Research Center of Powder Metallurgy, Powder Metallurgy Research Institute Central South University Changsha Hunan 410083 P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Han","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Digital Twin Eastern Institute of Technology  Ningbo Zhejiang 315200 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunxiao","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of Powder Metallurgy, Powder Metallurgy Research Institute Central South University Changsha Hunan 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3088-6549","authenticated-orcid":false,"given":"Weifeng","family":"Wei","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of Powder Metallurgy, Powder Metallurgy Research Institute Central South University Changsha Hunan 410083 P. R. 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