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While real\u2010time monitoring of water molecule dynamics during moisture sorption and desorption processes could provide crucial hygroscopic parameters for smart humidity regulation, conventional gravimetric methods suffer from low tracking speed, limited accuracy, and an inability to perform in situ detection. Here, we report a flexible hygroscopic electronics (FHE) capable of simultaneously regulating environmental moisture and dynamically monitoring sorption\u2010desorption processes through water\u2010mediated resistive changes in confined space. The targeted electronics exhibit exceptional performance, including a fast hygroscopic response of \u223c2.1 s at 90% RH, cycling stability, and stable sorption\u2010desorption properties over more than 50 cycles. By engineering a series of modular array\u2010based sensors, we achieve adjustable humidity control in enclosed spaces according to application\u2010specific requirements. As a proof\u2010of\u2010concept, the intelligent electronic array successfully maintains stable humidity conditions even in damaged equipment enclosures (&gt;3.5\u00a0h) and provides rapid sensory alerts. This work establishes an intelligent core\u2010shell FHE system, that absorbs unexpected moisture through a bio\u2010based hygroscopic core and simultaneously monitors the water sorption\/desorption behaviors by a thin conductive shell, which allows remote warning for potential seal risk of equipment in an early stage.<\/jats:p>","DOI":"10.1002\/adma.202518207","type":"journal-article","created":{"date-parts":[[2026,2,3]],"date-time":"2026-02-03T11:50:00Z","timestamp":1770119400000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Flexible Hygroscopic Electronics for Real\u2010Time Moisture Sorption\u2010Desorption Monitoring and Smart Humidity Regulation"],"prefix":"10.1002","volume":"38","author":[{"given":"Weiqing","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Zhejiang Key Laboratory of Extreme\u2010environmental Material Surfaces and Interfaces Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyi","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Zhejiang Key Laboratory of Extreme\u2010environmental Material Surfaces and Interfaces Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Zhejiang Key Laboratory of Extreme\u2010environmental Material Surfaces and Interfaces Ningbo Institute of Materials Technology and Engineering Chinese 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuchao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Zhejiang Key Laboratory of Extreme\u2010environmental Material Surfaces and Interfaces Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Zhejiang Key Laboratory of Extreme\u2010environmental Material Surfaces and Interfaces Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 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