{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T04:22:25Z","timestamp":1789878145001,"version":"4.0.1"},"reference-count":51,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T00:00:00Z","timestamp":1768867200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["22120240314"],"award-info":[{"award-number":["22120240314"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The practical deployment of high\u2010energy lithium\u2010sulfur (Li\u2010S) batteries is critically impeded by low sulfur utilization, primarily due to the shuttle effect of soluble polysulfides and, less investigated, the passivation of the deposited Li\n                    <jats:sub>2<\/jats:sub>\n                    S film. To address these challenges, we report an electrochemically in situ self\u2010generated Li\n                    <jats:sub>3<\/jats:sub>\n                    PS\n                    <jats:sub>4<\/jats:sub>\n                    molecules that serve as novel molecular mediators to guide the nucleation of Li\n                    <jats:sub>2<\/jats:sub>\n                    S preferentially on Li\n                    <jats:sub>3<\/jats:sub>\n                    PS\n                    <jats:sub>4<\/jats:sub>\n                    , forming a 3D assembly film composed of Li\n                    <jats:sub>3<\/jats:sub>\n                    PS\n                    <jats:sub>4<\/jats:sub>\n                    @Li\n                    <jats:sub>2<\/jats:sub>\n                    S molecular clusters with an optimized stoichiometry ratio (1:6), thereby effectively suppressing the aggregation and passivation of bulk Li\n                    <jats:sub>2<\/jats:sub>\n                    S. The Li\n                    <jats:sub>3<\/jats:sub>\n                    PS\n                    <jats:sub>4<\/jats:sub>\n                    mediators were cyclically generated during discharge from a cathode composed of a 3D phosphorus\u2010sulfur covalent inorganic framework (P\u2010S CIF) grown on Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    nanosheets (TNS). The P\u2010S CIF features a tetrahedral architecture with phosphorus atoms at vertices interconnected by sulfur chains, spatially confining sulfur species to minimize long\u2010chain polysulfides (Li\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>n<\/jats:sub>\n                    , n\u22656) generation. Benefiting from the synergistic effect of Li\n                    <jats:sub>3<\/jats:sub>\n                    PS\n                    <jats:sub>4<\/jats:sub>\n                    \u2010mediated Li\n                    <jats:sub>2<\/jats:sub>\n                    S nucleation plus the spatial confinement provided by the P\u2010S CIF, and the strong polysulfide anchoring capability of TNS, the TNS\/P\u2010S CIF cathode achieves exceptional stability and kinetics, delivering an initial capacity of 967 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and retaining 673 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 1000 cycles at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (decay rate: 0.022% per cycle). Notably, the electrode maintains an areal capacity of 6.24 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    under a high loading of 9.8\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , surpassing commercial benchmarks. This work establishes a molecular\u2010level design paradigm for sulfur hosts, integrating structural precision with electrochemical functionality to advance the practical realization of high\u2010performance Li\u2010S batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202519401","type":"journal-article","created":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T10:11:30Z","timestamp":1768903890000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Li\n                    <sub>2<\/sub>\n                    S Anti\u2010Passivation Deposition Guided by Electrochemically Self\u2010Generated Thiophosphate Molecular Mediators for Lithium\u2010Sulfur Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Lu","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemical Science and Engineering, and State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. 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