{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T17:55:35Z","timestamp":1793123735310,"version":"4.5.0"},"reference-count":54,"publisher":"Wiley","license":[{"start":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T00:00:00Z","timestamp":1765238400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52125306"],"award-info":[{"award-number":["52125306"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U24A2081"],"award-info":[{"award-number":["U24A2081"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379167"],"award-info":[{"award-number":["22379167"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004735","name":"Natural Science Foundation of Hunan Province","doi-asserted-by":"publisher","award":["2024JJ1013"],"award-info":[{"award-number":["2024JJ1013"]}],"id":[{"id":"10.13039\/501100004735","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004735","name":"Natural Science Foundation of Hunan Province","doi-asserted-by":"publisher","award":["2024JK2104"],"award-info":[{"award-number":["2024JK2104"]}],"id":[{"id":"10.13039\/501100004735","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Minimizing non\u2010radiative recombination loss remains a critical challenge for advancing the efficiency of organic solar cells (OSCs). Herein, a molecular design strategy based on a series of cyclic\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010conjugated electron acceptors is reported, RCM\u2010C6, RCM\u2010C5, and RCM\u2010C4, to effectively suppress non\u2010radiative loss pathways. Compared to their linear analogues, these cyclic molecules demonstrate a significantly enhanced photoluminescence quantum yield, exceeding 14%. This is achieved by effectively suppressing the high\u2010frequency vibrational modes, minimizing non\u2010radiative decay channels. Further, while cyclic molecules have historically suffered from unfavorable aggregation that impedes charge transport, this limitation has been overcome by systematically tuning the alkyl chain lengths on the RCM framework. This approach allows for precise control over molecular packing and optimization of thin\u2010film morphology. As a result, a high\u2010performance OSC is fabricated, achieving a power conversion efficiency of 17.1%, the highest reported for macrocycle\u2010based systems to date. This work demonstrates that macrocycle conjugated architecture provides an instructive approach to suppress non\u2010radiative recombination while maintaining efficient charge transport, establishing a new framework for rational design of next\u2010generation high\u2010performance organic photovoltaic materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.202519607","type":"journal-article","created":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T13:12:07Z","timestamp":1765285927000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Conformationally Locked Macrocyclic Acceptors with Enhanced Photoluminescence for High\u2010Efficiency Organic Solar Cells"],"prefix":"10.1002","author":[{"given":"Wei","family":"Liu","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"},{"name":"School of Metallurgy and Environment Central South University  Changsha Hunan 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Yuan","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yijie","family":"Nai","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nakul","family":"Jain","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Biology Link\u00f6ping University  Link\u00f6ping SE\u2010581 83 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenquan","family":"Fu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weikun","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials Soochow University  Soochow Jiangsu 215000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials Soochow University  Soochow Jiangsu 215000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huotian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Biology Link\u00f6ping University  Link\u00f6ping SE\u2010581 83 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueyi","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Metallurgy and Environment Central South University  Changsha Hunan 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Biology Link\u00f6ping University  Link\u00f6ping SE\u2010581 83 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1901-7243","authenticated-orcid":false,"given":"Yingping","family":"Zou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Central South University  Changsha 410083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/j.joule.2017.09.020","volume":"2","author":"Menke S. M.","year":"2018","journal-title":"Joule"},{"key":"e_1_2_7_2_1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.trechm.2019.01.010","volume":"1","author":"Azzouzi M.","year":"2019","journal-title":"Trends Chem."},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"2147","DOI":"10.1016\/j.chempr.2020.08.003","volume":"6","author":"Yuan J.","year":"2020","journal-title":"Chem"},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1038\/s41563-018-0128-z","volume":"17","author":"Qian D. P.","year":"2018","journal-title":"Nat. Mater."},{"key":"e_1_2_7_5_1","doi-asserted-by":"crossref","first-page":"711","DOI":"10.1038\/s41560-020-00684-7","volume":"5","author":"Classen A.","year":"2020","journal-title":"Nat. Energy"},{"key":"e_1_2_7_6_1","doi-asserted-by":"crossref","first-page":"6362","DOI":"10.1021\/jacs.9b01465","volume":"141","author":"Eisner F. D.","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1038\/s41563-024-02087-5","volume":"24","author":"Li C.","year":"2025","journal-title":"Nat. Mater."},{"key":"e_1_2_7_8_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202403675","volume":"37","author":"Jain N.","year":"2024","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_7_9_1","doi-asserted-by":"crossref","first-page":"799","DOI":"10.1038\/s41560-021-00843-4","volume":"6","author":"Chen X. K.","year":"2021","journal-title":"Nat. Energy"},{"key":"e_1_2_7_10_1","doi-asserted-by":"crossref","DOI":"10.1021\/jacs.0c08557","volume":"142","author":"Zhang Z.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_11_1","doi-asserted-by":"crossref","first-page":"3256","DOI":"10.1038\/s41467-022-30927-y","volume":"13","author":"Shi Y.","year":"2022","journal-title":"Nat. Commun."},{"key":"e_1_2_7_12_1","doi-asserted-by":"crossref","DOI":"10.1021\/jacs.4c01503","volume":"146","author":"Sun Y. D.","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_13_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202306471","volume":"33","author":"Si X. D.","year":"2023","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_7_14_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202300458","volume":"13","author":"Shi Y. A.","year":"2023","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_7_15_1","doi-asserted-by":"crossref","first-page":"1374","DOI":"10.1007\/s11426-022-1281-0","volume":"65","author":"Liu W.","year":"2022","journal-title":"Sci. China Chem."},{"key":"e_1_2_7_16_1","doi-asserted-by":"crossref","first-page":"8623","DOI":"10.1021\/acs.macromol.3c01636","volume":"56","author":"Liu W.","year":"2023","journal-title":"Macromolecules"},{"key":"e_1_2_7_17_1","doi-asserted-by":"crossref","first-page":"7192","DOI":"10.1021\/ja801422n","volume":"130","author":"Wu Y. G.","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_18_1","doi-asserted-by":"crossref","first-page":"300","DOI":"10.1038\/s41566-019-0573-5","volume":"14","author":"Liu S.","year":"2020","journal-title":"Nat. Photonics"},{"key":"e_1_2_7_19_1","doi-asserted-by":"crossref","first-page":"5079","DOI":"10.1038\/s41467-023-40806-9","volume":"14","author":"Jiang Y. Y.","year":"2023","journal-title":"Nat. Commun."},{"key":"e_1_2_7_20_1","doi-asserted-by":"crossref","first-page":"1140","DOI":"10.1016\/j.joule.2019.01.004","volume":"3","author":"Yuan J.","year":"2019","journal-title":"Joule"},{"key":"e_1_2_7_21_1","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1038\/s41467-019-08386-9","volume":"10","author":"Yuan J.","year":"2019","journal-title":"Nat. Commun."},{"key":"e_1_2_7_22_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202403747","volume":"14","author":"Pan Y. Y.","year":"2024","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_7_23_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202111855","volume":"32","author":"He D.","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_7_24_1","volume":"18","author":"Wei N.","year":"2025","journal-title":"ChemSusChem"},{"key":"e_1_2_7_25_1","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202001160","volume":"32","author":"Li S. X.","year":"2020","journal-title":"Adv. Mater."},{"key":"e_1_2_7_26_1","doi-asserted-by":"crossref","DOI":"10.1002\/adom.202202521","volume":"11","author":"Ye Z. C.","year":"2023","journal-title":"Adv. Opt. Mater."},{"key":"e_1_2_7_27_1","doi-asserted-by":"crossref","first-page":"2164","DOI":"10.1021\/jacs.0c12659","volume":"143","author":"Zhu H. T. Z.","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_28_1","doi-asserted-by":"crossref","first-page":"1482","DOI":"10.1021\/jacs.9b11578","volume":"142","author":"Izumi S.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_29_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202411745","volume":"34","author":"Zhang W. X.","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_7_30_1","doi-asserted-by":"crossref","first-page":"7850","DOI":"10.1039\/C8CC03833C","volume":"54","author":"Hu Y. Y.","year":"2018","journal-title":"Chem. Commun."},{"key":"e_1_2_7_31_1","volume":"62","author":"Shen S. S.","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"e_1_2_7_32_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.202507288","volume":"35","author":"Shen S. S.","year":"2025","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_7_33_1","first-page":"1","author":"Shen S. S.","year":"2025","journal-title":"CCS Chem."},{"key":"e_1_2_7_34_1","doi-asserted-by":"crossref","first-page":"2850","DOI":"10.1038\/s41467-022-30121-0","volume":"13","author":"Li S.","year":"2022","journal-title":"Nat. Commun."},{"key":"e_1_2_7_35_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202311645","volume":"62","author":"Liu W.","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"e_1_2_7_36_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.201904234","volume":"10","author":"Zhu L.","year":"2020","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_7_37_1","doi-asserted-by":"crossref","first-page":"440","DOI":"10.1002\/jccs.202100531","volume":"69","author":"Prakoso S. P.","year":"2022","journal-title":"J. Chin. Chem. Soc."},{"key":"e_1_2_7_38_1","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202301929","volume":"35","author":"Fu Y.","year":"2023","journal-title":"Adv. Mater."},{"key":"e_1_2_7_39_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202424276","volume":"64","author":"Han X. N.","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"e_1_2_7_40_1","doi-asserted-by":"crossref","DOI":"10.1002\/agt2.46","volume":"2","author":"Gao M. Y.","year":"2021","journal-title":"Aggregate"},{"key":"e_1_2_7_41_1","doi-asserted-by":"crossref","first-page":"2127","DOI":"10.1021\/ja208503y","volume":"134","author":"Bogdan A. R.","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_42_1","doi-asserted-by":"crossref","DOI":"10.1002\/adfm.201808828","volume":"29","author":"Liao Z. H.","year":"2019","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_7_43_1","doi-asserted-by":"crossref","DOI":"10.1002\/adom.202001845","volume":"9","author":"Qiu X.","year":"2021","journal-title":"Adv. Opt. Mater."},{"key":"e_1_2_7_44_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2021.131351","volume":"426","author":"Liu F. T.","year":"2021","journal-title":"Chem. Eng. J."},{"key":"e_1_2_7_45_1","doi-asserted-by":"crossref","first-page":"4726","DOI":"10.1021\/jacs.8b01805","volume":"140","author":"Kim S.","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_46_1","doi-asserted-by":"crossref","first-page":"9264","DOI":"10.1021\/ja060354b","volume":"128","author":"Seo S. H.","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_47_1","doi-asserted-by":"crossref","first-page":"1159","DOI":"10.1007\/s11426-020-9747-9","volume":"63","author":"Yuan J.","year":"2020","journal-title":"Sci. China Chem."},{"key":"e_1_2_7_48_1","doi-asserted-by":"crossref","first-page":"6315","DOI":"10.1021\/acs.macromol.5c00411","volume":"58","author":"Liu W.","year":"2025","journal-title":"Macromolecules"},{"key":"e_1_2_7_49_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.201503219","volume":"54","author":"Chen P. K.","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"e_1_2_7_50_1","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1038\/s41586-024-07246-x","volume":"629","author":"Ghosh P.","year":"2024","journal-title":"Nature"},{"key":"e_1_2_7_51_1","doi-asserted-by":"crossref","DOI":"10.1038\/nenergy.2017.53","volume":"2","author":"Benduhn J.","year":"2017","journal-title":"Nat. Energy"},{"key":"e_1_2_7_52_1","doi-asserted-by":"crossref","first-page":"3679","DOI":"10.1039\/D0EE01896A","volume":"13","author":"Karki A.","year":"2020","journal-title":"Energy Environ. Sci."},{"key":"e_1_2_7_53_1","doi-asserted-by":"crossref","DOI":"10.1039\/D5CC04548G","volume":"61","author":"Liu W.","year":"2025","journal-title":"Chem. Commun."},{"key":"e_1_2_7_54_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202312630","volume":"62","author":"Yao Z. Y.","year":"2023","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202519607","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,9]],"date-time":"2025-12-09T13:12:14Z","timestamp":1765285934000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202519607"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,9]]},"references-count":54,"alternative-id":["10.1002\/adma.202519607"],"URL":"https:\/\/doi.org\/10.1002\/adma.202519607","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,9]]},"assertion":[{"value":"2025-10-05","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e19607"}}