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However, the intrinsic plasticizing effect and network dilution caused by ionic liquids (IL) compromise their mechanical robustness. Herein, a confinement\u2010locking strategy is developed to produce mechanically robust and fatigue\u2010resistant phase\u2010separate ionogels. First, a portion of soft segments is confined within the hard domains to buffer stress and facilitate hydrogen bonding (H\u2010bonding) assemblies reorganization. Second, the IL are confined within soft phases, which eliminates the interference with hard segments and consequently enhances the stability of H\u2010bonding networks. The synergistic effects of robust H\u2010bonding networks, extensive supramolecular interactions between soft segments (polycaprolactone, PCL) and IL, strain\u2010induced crystallization of PCL, and stress\u2010damping by confined soft segments endow the ionogel with an exceptional combination of tensile strength (\u223c45.4\u00a0MPa), fracture toughness (256.1 MJ\u00b7m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>3<\/jats:sup>\n                    ), elongation at break (1576.6%), elastic recovery (&gt;91%), ionic conductivity (1.04 mS\u00b7cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), tear strength (\u223c108.1 kJ\u00b7m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ), and a record\u2010high fatigue threshold (8796 J\u00b7m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ), enabling the ionogel with great potential in perceptive artificial ligaments.\n                  <\/jats:p>","DOI":"10.1002\/adma.202520126","type":"journal-article","created":{"date-parts":[[2025,12,26]],"date-time":"2025-12-26T10:13:04Z","timestamp":1766743984000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Confinement\u2010Locking Strategy Enables Ionogels With Remarkable Mechanical Robustness and Fatigue Resistance"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3146-6703","authenticated-orcid":false,"given":"Haiming","family":"Chen","sequence":"first","affiliation":[{"name":"Laboratory of Polymers and Composites Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"Ningbo Key Laboratory of High\u2010Performance Polymers and Composites  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengyi","family":"Huang","sequence":"additional","affiliation":[{"name":"Laboratory of Polymers and Composites Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"Ningbo Key Laboratory of High\u2010Performance Polymers and Composites  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Marine Materials Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanzi","family":"Gao","sequence":"additional","affiliation":[{"name":"Institute For Advanced Materials and Technology University of Science and Technology Beijing  Beijing 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