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Here we introduce a radial\u2010effect design principle: relativistic expansion and spin\u2013orbit coupling of 5\n                    <jats:italic>d<\/jats:italic>\n                    orbitals enhance\n                    <jats:italic>s\u2013d<\/jats:italic>\n                    \/\n                    <jats:italic>p\u2013d<\/jats:italic>\n                    hybridization, weaken Li\u2013anion interactions, and lower migration barriers. An entropy\u2010based descriptor,\n                    <jats:italic>\n                      S\n                      <jats:sub>d<\/jats:sub>\n                    <\/jats:italic>\n                    , trained and validated with machine learning across &gt;10,000 oxides, sulfides, and halides captures this effect. Machine\u2010learning\u2010guided high\u2010throughput screening flags monoclinic HfO\n                    <jats:sub>2<\/jats:sub>\n                    , whose 5\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    radial expansion lowers migration barriers by \u223c45% vs Sc\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    or Y\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    . Guided by this insight, we employ millisecond flash\u2010Joule heating to convert HfO\n                    <jats:sub>2<\/jats:sub>\n                    into nanosized single crystals, then embed them in a Li\u2010conductive binder to create sc\u2010HfO\n                    <jats:sub>2<\/jats:sub>\n                    @LCB, whose radial coupling yields interconnected Li\n                    <jats:sup>+<\/jats:sup>\n                    pathways (1.23 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 30\u00b0C;\n                    <jats:italic>t<\/jats:italic>\n                    <jats:sub>\n                      <jats:italic>Li<\/jats:italic>\n                      +\n                    <\/jats:sub>\n                    = 0.82, 25\u00b0C) and a 4.8\u00a0V electrochemical window. Operando Raman\/XANES confirms faster Li\n                    <jats:sup>+<\/jats:sup>\n                    transport. Consequently, 2 Ah LiNi\n                    <jats:sub>0.9<\/jats:sub>\n                    Co\n                    <jats:sub>0.05<\/jats:sub>\n                    Mn\n                    <jats:sub>0.05<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    \u2016Li pouch cells deliver \u223c472\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    (stack\u2010level), maintain superior rate capability over hundreds of cycles, and survive 150\u00b0C hot\u2010plate tests. These results establish radial\u2010effect engineering as a sophisticated strategy for high\u2010performance, thermally resilient solid\u2010state batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202520337","type":"journal-article","created":{"date-parts":[[2026,1,25]],"date-time":"2026-01-25T07:14:43Z","timestamp":1769325283000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Engineering Electronic Radial Effects for Fast Li\n                    <sup>+<\/sup>\n                    Transport in Solid\u2010State Electrolytes"],"prefix":"10.1002","volume":"38","author":[{"given":"Jiadong","family":"Shen","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gilseob","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jong\u2010woan","family":"Chung","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sunjae","family":"Kwon","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wootack","family":"Chung","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dahye","family":"Yoon","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiwen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering National University of Singapore  Singapore Singapore"},{"name":"School of Mechanical Engineering Southeast University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Shen","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering National University of Singapore  Singapore Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology  Singapore Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering South 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