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Herein, we report the versatile and scalable one\u2010pot solvothermal synthesis of a series of RuFeMMnMo (M\u2550CoNi, Co, and Ni) high\u2010entropy alloy (HEA) nanomaterials, possessing a unique face\u2010centered cubic\u2010hexagonal close\u2010packed\u2010face\u2010centered cubic (\n                    <jats:italic>fcc\u2010hcp\u2010fcc<\/jats:italic>\n                    ) heterophase. The highly random distribution of multiple metal components and the tunable diversity of metal atomic arrangements can be realized simultaneously. Significantly, RuFeCoNiMnMo HEAs present a high Faradaic efficiency of 99.3\u2009% and a promising yield rate of 83.35\u00a0mg\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0mg\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    toward ammonia production at \u22120.6\u00a0V vs. reversible hydrogen electrode. Ex\/in situ characterizations and theoretical calculations have revealed that by high electron coupling of high\u2010entropy effect, heterophase\n                    <jats:italic>fcc\u2010hcp\u2010fcc<\/jats:italic>\n                    RuFeCoNiMnMo HEAs have shown strong electronic modulations with charge redistributions. The positive charges and negative charges for Ru sites and Ni\/Co sites promote the adsorption of key intermediates and generation of active protons, respectively, which guarantees efficient nitrate reduction due to the reduced energy barriers.\n                  <\/jats:p>","DOI":"10.1002\/adma.202521096","type":"journal-article","created":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T11:13:13Z","timestamp":1769080393000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Heterophase\n                    <i>fcc\u2010hcp\u2010fcc<\/i>\n                    High\u2010Entropy Alloy Nanomaterials with Tailored Electron Divergence for Selective Ammonia Electrosynthesis"],"prefix":"10.1002","volume":"38","author":[{"given":"Xiang","family":"Meng","sequence":"first","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious 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