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Here, we re\u2010examine this solvent selection rule and reveal that the cyclic consumption of Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010solvent complexes at the graphite electrode and their regeneration at the counter electrode leads to a net cancellation of solvation energy in coupled electrode systems, thereby decoupling solvation power from co\u2010intercalation feasibility. To validate this decoupling, we designed a fluorinated ether with deliberately attenuated solvating power but high reductive stability, as a proof\u2010of\u2010concept solvent. Successful co\u2010intercalation was observed with this weakly solvating fluorinated ether, whereas typical carbonate solvents with superior solvation capability failed due to reductive decomposition above the intercalation threshold, confirming that solvation strength is not the determining factor. Leveraging this insight, we further designed and identified aminated ethers as a previously unexplored subclass of ethers capable of co\u2010intercalation. This work revises the empirical dual\u2010factor rule and eliminates solvation capability as a constraint, which broadens the range of viable solvents for graphite\u2010based sodium\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202521350","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T07:23:37Z","timestamp":1778570617000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Revised Solvent Rule Unlocks Non\u2010Conventional Solvents for Na\n                    <sup>+<\/sup>\n                    \u2010Solvent Co\u2010Intercalation in Graphite"],"prefix":"10.1002","volume":"38","author":[{"given":"Yuanyuan","family":"Yang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Ocean University of China  Qingdao China"},{"name":"Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess 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