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The emergence of 2D van der Waals (vdW) magnets has introduced new opportunities for exploring proximity effects in vdW heterostructures. While the influence of magnetic layers on nearby non\u2010magnetic materials has been widely studied, it remains unclear whether non\u2010magnetic substrates can similarly modulate the intrinsic magnetic properties of 2D magnets, particularly their magnetic anisotropy. In this work, by analyzing X\u2010ray magnetic circular dichroism spectra of an epitaxially grown FeCl\n                    <jats:sub>2<\/jats:sub>\n                    monolayer on a Bi(111) surface, a reorientation of magnetic anisotropy is observed \u2013 from its natural out\u2010of\u2010plane to a predominantly in\u2010plane alignment. This effect vanishes in bilayer FeCl\n                    <jats:sub>2<\/jats:sub>\n                    \/Bi(111), where the magnetic anisotropy reverts to its intrinsic out\u2010of\u2010plane orientation, consistent with the layered antiferromagnetic order of bulk FeCl\n                    <jats:sub>2<\/jats:sub>\n                    . Angle\u2010resolved photoelectron spectroscopy reveals the presence of metallic interface states derived from the Bi surface states, accompanied by charge transfer and emergence of a moir\u00e9 potential that gives rise to a distinctive trefoil\u2010shaped Fermi surface. These results demonstrate that non\u2010magnetic substrates can exert strong proximity influence on the magnetic and electronic behavior of 2D vdW magnets, offering new strategies for engineering magnetic anisotropy and electronic structure in spintronic\u00a0heterostructures.\n                  <\/jats:p>","DOI":"10.1002\/adma.202521534","type":"journal-article","created":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T12:43:44Z","timestamp":1771505024000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Proximity Induced Magnetic Anisotropy and Trefoil Fermiology in Monolayer FeCl\n                    <sub>2<\/sub>\n                    \/Bi(111)"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5790-7234","authenticated-orcid":false,"given":"Shigemi","family":"Terakawa","sequence":"first","affiliation":[{"name":"Department of Applied Physics Graduate School of Engineering 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