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Among various molecular design strategies, the incorporation of heavy chalcogen elements has emerged as an effective approach to regulate excited\u2010state dynamics and enhance device performance. Owing to their unique electronic configurations, tunable oxidation states, and heavy\u2010atom effects, sulfur and selenium play crucial roles in modulating emission properties, strengthening spin\u2013orbit coupling, and promoting exciton utilization of thermally activated delayed fluorescence (TADF) and room\u2010temperature phosphorescence (RTP) systems. In recent years, significant progress has been made in integrating these elements into diverse emissive frameworks, including donor\u2013acceptor type TADF architectures, multiple\u2010resonance TADF systems, and purely organic RTP materials. Beyond emissive materials, sulfur\u2010containing units have also been explored as components of host materials for phosphorescent OLEDs. 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