{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T18:21:26Z","timestamp":1784053286565,"version":"3.55.0"},"reference-count":28,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T00:00:00Z","timestamp":1770336000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T00:00:00Z","timestamp":1770336000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22575061"],"award-info":[{"award-number":["22575061"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22205043"],"award-info":[{"award-number":["22205043"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100020084","name":"Guangzhou Municipal Science and Technology Bureau","doi-asserted-by":"publisher","award":["2025A04J5425"],"award-info":[{"award-number":["2025A04J5425"]}],"id":[{"id":"10.13039\/501100020084","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100020084","name":"Guangzhou Municipal Science and Technology Bureau","doi-asserted-by":"publisher","award":["2023A04J1408"],"award-info":[{"award-number":["2023A04J1408"]}],"id":[{"id":"10.13039\/501100020084","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003453","name":"Natural Science Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2022B1515020020"],"award-info":[{"award-number":["2022B1515020020"]}],"id":[{"id":"10.13039\/501100003453","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Photocatalytic oxidation of methane to formaldehyde at concentrations compatible with direct fuel\u2010cell use remains a critical yet unmet challenge. Here we introduce a \u201cdual\u2010gas coadsorption domain\u201d architecture discovered through a high\u2010throughput screen of 37 earth\u2010abundant transition metals and their oxides. Reduced nickel oxide (NiO\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    ) emerged as the optimal co\u2010catalyst, decorating the pore edges of vacancy\u2010rich porous ZnO (pZnO). Oxygen vacancies in pZnO act as oxygen pumps, while adjacent NiO\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    nanoclusters chemisorb and polarize methane, lowering the C\u2010H activation barrier and steering the radical cascade toward methyl hydroperoxide instead of methanol. Methyl hydroperoxide quantitatively decomposes to formaldehyde, delivering 28.5\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    (3\u00a0mM in solution, 88.5% selectivity). An outdoor reactor powered only by natural sunlight (peak 72.8\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) produced 12.3\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    formaldehyde in 6\u00a0h without detectable by\u2010products. The concentrated effluent feeds an alkaline formaldehyde fuel cell directly\u2014no purification\u2014co\u2010generating 0.2\u00a0kWh of electricity and valuable formate at a peak power density of 32.6\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The work establishes a scalable, solar\u2010driven pathway for simultaneous methane valorization and on\u2010site energy conversion.\n                  <\/jats:p>","DOI":"10.1002\/adma.202521696","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T09:27:36Z","timestamp":1770370056000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Dual\u2010Gas Activation Nanodomains Enable Solar\u2010Powered Selective Methane Conversion"],"prefix":"10.1002","volume":"38","author":[{"given":"Xiaoxin","family":"Liu","sequence":"first","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunru","family":"Ma","sequence":"additional","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaoguo","family":"Wang","sequence":"additional","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lifang","family":"Gao","sequence":"additional","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Du","sequence":"additional","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuheng","family":"Jiang","sequence":"additional","affiliation":[{"name":"Laboratory of Industrial Chemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Niu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Sun Yat\u2010sen University  Zhuhai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7944-2044","authenticated-orcid":false,"given":"Yingying","family":"Fan","sequence":"additional","affiliation":[{"name":"Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and Devices Guangdong Engineering Technology Research Center for Photoelectric Sensing Materials and Devices C\/O School of Chemistry and Chemical Engineering Guangzhou University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiyong","family":"Tang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Science (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,6]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA02793F"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA09592B"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.3c01941"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302950"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318989"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504894"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13313"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04884"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201030434\u20100"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09141"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201038334\u20107"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202406119"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11440"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119661"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201059465\u2010z"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049138\u20108"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010021\u201000682\u2010x"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06925"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001401\u2010y"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b01074"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1551\u20102916.2011.05030.x"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/b718768h"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302746"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1113955"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp211171t"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201036977\u20100"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201030532\u2010z"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.07.020"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202521696","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202521696","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202521696","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T11:27:39Z","timestamp":1773401259000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202521696"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,6]]},"references-count":28,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2026,3]]}},"alternative-id":["10.1002\/adma.202521696"],"URL":"https:\/\/doi.org\/10.1002\/adma.202521696","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,6]]},"assertion":[{"value":"2025-11-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-03","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e21696"}}