{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T01:23:46Z","timestamp":1780363426785,"version":"3.54.1"},"reference-count":69,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T00:00:00Z","timestamp":1768435200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T00:00:00Z","timestamp":1768435200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22205141"],"award-info":[{"award-number":["22205141"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22225501"],"award-info":[{"award-number":["22225501"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["W2412102"],"award-info":[{"award-number":["W2412102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["24CL2900100"],"award-info":[{"award-number":["24CL2900100"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["GA\u2010101135196"],"award-info":[{"award-number":["GA\u2010101135196"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2025X010202131"],"award-info":[{"award-number":["2025X010202131"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    2D bismuth possesses a unique combination of properties, such as cryogenic\u2010free quantum spin Hall effects and intrinsic single\u2010element ferroelectricity, making it highly promising for next\u2010generation electronic devices. However, the synthesis of 2D bismuth via exfoliation or direct growth is hindered by the low structural anisotropy of bulk bismuth crystals. To address this challenge, we demonstrate an unprecedented ice\u2010confined bottom\u2010up strategy for growing 2D bismuth. This approach involves kinetically controlled nucleation in liquid nitrogen (\u2010196\u00a0\u00b0C), followed by redox\u2010driven anisotropic growth within the confined space between ice and aluminum surfaces at \u221220\u00a0\u00b0C. The surfactant\u2010free process yields solution\u2010processable crystalline 2D bismuth with micrometer\u2010scale lateral dimensions and atomic\u2010level thickness, where 72% of the sheets are 1\u20133 layers thick. Thanks to its oxophilic surfaces, the as\u2010grown 2D bismuth effectively captures CO\n                    <jats:sub>2<\/jats:sub>\n                    molecules and facilitates their conversion to *OCHO intermediates during electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction, leading to an excellent formate Faraday efficiency of 95.6%. Moreover, this versatile synthetic route can be extended to other functional 2D metals, including silver, copper, and tellurium, thereby opening new avenues for the design of advanced catalysis, electronics, and related technologies.\n                  <\/jats:p>","DOI":"10.1002\/adma.202522192","type":"journal-article","created":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T05:44:48Z","timestamp":1768542288000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["On\u2010Surface Synthesis of Bismuth Monolayers through Ice\u2010Confined Redox Reactions"],"prefix":"10.1002","volume":"38","author":[{"given":"Zexiang","family":"He","sequence":"first","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Depeng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Science  Changchun Jilin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wentao","family":"Fan","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Songlin","family":"Liu","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antonio Gaetano","family":"Ricciardulli","sequence":"additional","affiliation":[{"name":"University of Strasbourg &amp; CNRS ISIS &amp; icFRC 8 all\u00e9e Gaspard Monge Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haixia","family":"Zhong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Science  Changchun Jilin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiyong","family":"Mai","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6256-8281","authenticated-orcid":false,"given":"Paolo","family":"Samor\u00ec","sequence":"additional","affiliation":[{"name":"University of Strasbourg &amp; CNRS ISIS &amp; icFRC 8 all\u00e9e Gaspard Monge Strasbourg France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng","family":"Yang","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for Transformative Molecules State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,15]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aai8142"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c09592"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-05848-5"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.132.116601"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008029"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms10814"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aba2773"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.110.165411"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04897"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206276"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202205997"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008316"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-56975-8"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005577"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202164"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1226419"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303929"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201911428"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808846"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702076"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801265"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015627"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00232-z"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NR06797J"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-025-08711-x"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4313"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/35097046"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR05578F"},{"key":"e_1_2_8_30_1","first-page":"17357","article-title":"Synthesis of Few\u2010Layer Bismuthene for Efficient Electroreduction of CO2 to Formate","volume":"6","author":"Wang X.","year":"2023","journal-title":"Nano Mater"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00551J"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b05188"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-14914-9"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9563"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201809662"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902352"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13036"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301597"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201703288"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg700851x"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.0c00953"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202309252"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902431"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0080-8"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aay9322"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adi9531"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2940195"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201711128"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202100910"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.05.001"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.130"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03712-z"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111905"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c06019"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202102629"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400813"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202307741"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00122"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c03573"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303889"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202203794"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301984"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104747"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317628"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415726"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.59.1758"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20495"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4865107"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202522192","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202522192","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202522192","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T10:32:23Z","timestamp":1777545143000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202522192"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,15]]},"references-count":69,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/adma.202522192"],"URL":"https:\/\/doi.org\/10.1002\/adma.202522192","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,15]]},"assertion":[{"value":"2025-11-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-07","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e22192"}}