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Among recent developments, localized high\u2010concentration electrolytes (LHCEs) have demonstrated remarkable cycling stability. However, their reliance on fluorinated diluents, which are highly reactive with lithium metal, inevitably leads to severe spontaneous corrosion. This study introduces a fluorine\u2010free, corrosion\u2010resistant diluent (CRD) strategy, employing benzene as the CRD in combination with amphiphilic butyl methyl ether as the primary solvent. This electrolyte design simultaneously extends both cycle and calendar life by promoting an anion\u2010dominated solvation structure, while the diluent effectively suppresses lithium metal corrosion. As a result, the CRD\u2010based electrolyte exhibits outstanding durability and stability compared to conventional LHCEs. Moreover, the fluorine\u2010free and cost\u2010effective electrolyte\u2013diluent system offers strong advantages for practical applications. Overall, this study demonstrates the potential of the CRD strategy to achieve stable electrode\u2013electrolyte interfaces and provides broader insights for diverse battery chemistries.<\/jats:p>","DOI":"10.1002\/adma.202522875","type":"journal-article","created":{"date-parts":[[2026,1,25]],"date-time":"2026-01-25T07:07:00Z","timestamp":1769324820000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Fluorine\u2010Free Corrosion\u2010Resistant Electrolyte Design for Enhanced Stability in Lithium Metal Batteries"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-2090-5462","authenticated-orcid":false,"given":"Hyeonmin","family":"Jo","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Hanyang University  Seoul Republic of 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