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However, acidic media and high oxidation potential can lead to oxidative dissolution of catalysts (e.g., RuO\n                    <jats:sub>2<\/jats:sub>\n                    \u2192 soluble RuO\n                    <jats:sub>4<\/jats:sub>\n                    ), resulting in a rapid loss of active sites. Here, we present an inter\u2010doping strategy for the construction of zirconium\u2010ruthenium oxide heterostructure (ZrO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010xRuO\n                    <jats:sub>2<\/jats:sub>\n                    ) through metal\u2013organic framework confined effect and fused salt mixing method. Specifically, ZrO\n                    <jats:sub>2<\/jats:sub>\n                    \u20105.5RuO\n                    <jats:sub>2<\/jats:sub>\n                    achieves an ultralow overpotential of 137\u00a0mV at 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , setting a new benchmark for oxygen evolution catalysts under acidic conditions. Its mass activity (337.5\u00a0A g\n                    <jats:sub>Ru<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) at 250\u00a0mV overpotential is 32.3 times that of commercial RuO\n                    <jats:sub>2<\/jats:sub>\n                    . The catalyst also demonstrates long\u2010term stability for 655\u00a0h, far superior to commercial RuO\n                    <jats:sub>2<\/jats:sub>\n                    (&lt;6\u00a0h). The remarkable activity and stability can be attributed to the Zr\u2500O\u2500Ru interfacial junction, resulting in low\u2010valence Ru sites and high\u2010valence Zr sites. The charge redistribution optimizes the adsorption energy of reactive oxygen species and minimizes the involvement of lattice oxygen, thus leading to a significant enhancement in both activity and stability. This work provides a novel insight for addressing the activity\u2010stability dilemma through atomic\u2010level interface engineering, establishing a new paradigm for the large\u2010scale application of green hydrogen energy.\n                  <\/jats:p>","DOI":"10.1002\/adma.202522946","type":"journal-article","created":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T05:34:32Z","timestamp":1768541672000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Inter\u2010Doping ZrO\n                    <sub>2<\/sub>\n                    \u20105.5RuO\n                    <sub>2<\/sub>\n                    Heterostructures for Enhanced Efficiency and Stability in Acidic Oxygen Evolution"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9409-6303","authenticated-orcid":false,"given":"Peisen","family":"Liao","sequence":"first","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binning","family":"Zeng","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijia","family":"Zhan","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"YunTao","family":"Ruan","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yawei","family":"Zhang","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Shen","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1233-5591","authenticated-orcid":false,"given":"Guangqin","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional Materials School of Chemistry Sun Yat\u2010Sen University  Guangzhou P. R. 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