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Herein, we report an ultrathin (27\u00a0\u00b5m) mesoporous ionic brushes (MiB) separator based on sulfonic grafted ordered mesoporous silica nanosheets for stable ZnABs. The well\u2010ordered perforative mesopores architecture functions as an ion rectifier that achieves enhanced transfer kinetics and a homogeneous concentration field, thereby promoting dendrite\u2010free deposition, as verified by in situ digital holography and kinetic analyses. Moreover, ionic brushes confined within nanochannels selectively capture water molecules from the primary solvation shell of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , facilitating desolvation and constructing a localized water\u2010lean interfacial environment, which effectively suppresses water\u2010related side reactions, as evidenced by various in situ spectroscopy, electrochemical analyses, and theoretical calculations. Consequently, the MiB separator enables the Zn anode to achieve a high Coulombic efficiency of 99.7%, ultralong lifespan over 4300\u00a0h, fast plating kinetics of 20\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and high Zn utilization rate of 51.6%. Furthermore, Zn\u2010V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    cells achieve perdurable capacity retention of 91.5% after 3500 cycles. This work presents a rational mesoporous separator design that synchronously regulates ion transport and interfacial solvation chemistry for highly reversible ZnABs.\n                  <\/jats:p>","DOI":"10.1002\/adma.202523619","type":"journal-article","created":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T15:25:57Z","timestamp":1770823557000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Ultrathin Mesoporous Ionic Brushes Separator Enables Fast and Durable Zinc\u2010Metal Aqueous Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Yucai","family":"Wu","sequence":"first","affiliation":[{"name":"Department of Chemistry Laboratory of Advanced Materials Aqueous Battery Center Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Shanghai Wusong Laboratory of Materials Science Collaborative Innovation Center of Chemistry for Energy Materials State Key Laboratory of Porous 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