{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T03:02:57Z","timestamp":1790391777400,"version":"4.1.0"},"reference-count":59,"publisher":"Wiley","issue":"54","license":[{"start":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T00:00:00Z","timestamp":1777248000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T00:00:00Z","timestamp":1777248000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373316"],"award-info":[{"award-number":["52373316"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFF0728500"],"award-info":[{"award-number":["2024YFF0728500"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Precise molecular design and orthogonal reaction pathways offer powerful tools for engineering polymer networks with controlled nanoscale architectures and advanced dielectric properties. Herein, we report an orthogonal monomer design strategy that integrates ring\u2010opening metathesis polymerization (ROMP), photodimerization, and thermally induced benzocyclobutene (BCB) crosslinking to construct hybrid polymers with sequentially cured, nanoconfined silsesquioxane (SSQ) domains. The modular incorporation of photoreactive anthracene and thermally active BCB units into ROMP\u2010compatible monomers enables chemically decoupled dual curing. This sequential crosslinking allows precise spatial confinement of SSQ domains within a covalent organic matrix, effectively minimizing interfacial defects and phase separation. The resulting hybrid networks exhibit an ultralow dielectric constant (\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>k<\/jats:sub>\n                    = 2.08), extremely low dissipation factor (\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>f<\/jats:sub>\n                    = 6.67 \u00d7 10\n                    <jats:sup>\u22124<\/jats:sup>\n                    ), high thermal stability (the 5% weight loss temperature,\n                    <jats:italic>\n                      T\n                      <jats:sub>d5<\/jats:sub>\n                    <\/jats:italic>\n                    &gt; 400\u00b0C), hydrophobic surfaces (water contact angle &gt; 100\u00b0), and robust mechanical integrity. This work highlights a generalizable chemical design paradigm that links orthogonal monomer reactivity to nanoscale structure control and multifunctional dielectric performance, offering a promising pathway for advanced electronic packaging materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.202600007","type":"journal-article","created":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T06:22:40Z","timestamp":1777357360000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Orthogonal Monomer Design Enables Sequentially Cured Hybrid Polymers for Ultralow\u2010Dielectric Applications"],"prefix":"10.1002","volume":"38","author":[{"given":"Xiaohao","family":"Tang","sequence":"first","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Xie","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Xue","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8986-8310","authenticated-orcid":false,"given":"Wenxing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenxin","family":"Fu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Science and Technology on High\u2010Tech Polymer Materials Institute of Chemistry Chinese Academy of Sciences  Beijing P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,27]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/ppap.201900039"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513483"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202411082"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0079\u20106700(00)00043\u20105"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00542\u2010013\u20101765\u20104"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.optmat.2017.03.014"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201302021"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mne.2024.100258"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202517027"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502146"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507704"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.3c00351"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c14298"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2023.126188"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/d2py00234e"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.201900017"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/mame.201900505"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000238"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000166"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c08159"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.9b00519"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2020.109562"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2023.101972"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/pc.27915"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118\u2010025\u20103296\u20108"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118\u2010023\u20102955\u2010x"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2018.09.005"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.3390\/jcs5010011"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00301"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.2c00670"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409112"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900470"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313971"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.3c02003"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202102074"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2020.101209"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/a801821i"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/c5ra27647k"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26208"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10971\u2010022\u201005920\u2010y"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.3390\/gels8100677"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10246"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/c7tc04220e"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305611"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201035837\u20101"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biomac.2c00280"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202000600"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.1c01337"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/c7ra00141j"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.52614"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.49074"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2012.01.006"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/d1tc06041d"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.47465"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/c9py00719a"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.51376"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.47458"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2022.100782"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135737"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202600007","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202600007","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202600007","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T02:39:33Z","timestamp":1790390373000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202600007"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,27]]},"references-count":59,"journal-issue":{"issue":"54","published-print":{"date-parts":[[2026,9]]}},"alternative-id":["10.1002\/adma.202600007"],"URL":"https:\/\/doi.org\/10.1002\/adma.202600007","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,27]]},"assertion":[{"value":"2026-01-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-22","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e00007"}}