{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T14:13:01Z","timestamp":1790345581267,"version":"4.1.0"},"reference-count":36,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T00:00:00Z","timestamp":1773792000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T00:00:00Z","timestamp":1773792000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578352"],"award-info":[{"award-number":["22578352"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017596","name":"Natural Science Basic Research Program of Shaanxi Province","doi-asserted-by":"publisher","award":["2025JC\u2010QYCX\u2010011"],"award-info":[{"award-number":["2025JC\u2010QYCX\u2010011"]}],"id":[{"id":"10.13039\/501100017596","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Traditional O3\u2010type layered oxides with edge\u2010sharing (ES) octahedra suffer from structural instability under high\u2010voltage operation. To address this, we propose a stable edge\u2010sharing coplanar (ESC) O2\u2010type layered structure. In this structure, Li\u2013O octahedra share edges on one side and faces on the other with Co\u2013O octahedra. This ESC\u2010configuration effectively suppresses Co migration and enhances intrinsic structural stability. Furthermore, the 180\u00b0Ni\u2013O\u2013TM (TM = paramagnetic transition metal) super\u2010exchange interactions along the edge\u2010sharing directions are introduced to improve high\u2010voltage cycling stability. With an optimal amount of Ni, the unit\u2010cell volume expands, reducing the activation energy for Li\u2010ion diffusion. As a result, the modified ESC\u2010cathode delivers a high discharge capacity of 247\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a capacity retention of 79% at 1 C after 100 cycles between 3.0 and 4.65\u00a0V, far exceeding that of conventional edge\u2010sharing LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    (210\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 26%). Interestingly, unlike in conventional edge\u2010sharing layered cathodes, where Ni contributes directly to capacity, increasing Ni content in ESC cathodes leads to a decrease in capacity because additional Ni ions enter the Li layer and obstruct Li\u2010ion diffusion pathways. Overall, this work presents an effective strategy for regulating the local coordination environment of layered oxide cathodes to achieve high performance.\n                  <\/jats:p>","DOI":"10.1002\/adma.72851","type":"journal-article","created":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T14:34:46Z","timestamp":1773844486000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Alternating Edge\u2010 and Face\u2010Sharing Octahedra with Partial Super\u2010Exchange Enabling High\u2010Voltage Layered Cathodes"],"prefix":"10.1002","volume":"38","author":[{"given":"Qin","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu China"},{"name":"School of Chemical Engineering and Technology State Key Laboratory of Electrical Insulation and Power Equipment School of Instrument Science and Technology Xi'an Jiaotong University  Xi'an 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