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As the increasing energy crisis and environmental concern, the conversion of shale gas to value\u2010added chemical in a sustainable manner has emerged as a new frontier yet remains great challenges. Herein, we realize the solar\u2010driven conversion of shale gas into alcohols over ZnO nanomeshes incorporated with Ni nanoparticles (Ni\/ZnO NM) with oxygen and water. Specifically, the isopropanol yield from C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    oxidation reaches 7.1\u00a0mmol \u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009 h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a selectivity of 83.5%, with an apparent quantum efficiency (AQE) of 0.65% at 350\u00a0nm, surpassing the reported catalysts for propane\u2010to\u2010oxygenates. Moreover, both the selectivity of methanol and ethanol surpass 90% from solar\u2010driven CH\n                    <jats:sub>4<\/jats:sub>\n                    and C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    oxidation. Impressively, a mixture of methane, ethane, and propane, the analogue of shale gas, can be selectively converted into methanol, ethanol, and isopropanol. Mechanism studies suggest the strong interaction induces electron transfer from ZnO to Ni and creates electron\u2010rich Ni sites and electron\u2010deficient oxygen vacancies (Vo) in ZnO NM. Under light irradiation, electron\u2010rich Ni sites and electron\u2010deficient Vo can serve as hole and electron acceptors, respectively, promoting the separation of photogenerated carriers and enhancing performance toward alkane oxidation.\n                  <\/jats:p>","DOI":"10.1002\/adma.72867","type":"journal-article","created":{"date-parts":[[2026,3,21]],"date-time":"2026-03-21T14:30:02Z","timestamp":1774103402000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Direct Photoconversion of Shale Gas into Liquid Oxygenates Over Interfacially Coupled Ni\/ZnO Nanomesh"],"prefix":"10.1002","volume":"38","author":[{"given":"Fei","family":"Xue","sequence":"first","affiliation":[{"name":"i\u2010lab of Suzhou Institute of Nano\u2010Tech and Nano\u2010Bionics (SINANO) Chinese Academy of Sciences (CAS)  Suzhou China"},{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenlong","family":"Fu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Mechanical Behavior of Materials Shaanxi International Research Center for Soft Matter School of Materials Science and Engineering Xi'an Jiaotong University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Cheng","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Xi'an Jiaotong University  Xi'an 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