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Here, a quasi\u2010solid\u2010state redox pathway is activated via an unsaturated coordination chemistry strategy, in which unsaturated MoS\n                    <jats:sub>2<\/jats:sub>\n                    anchored on cross\u2010linked carbon microspheres forms a multifunctional sulfur host (S@U\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    \/C) that combines strong polysulfide adsorption with accelerated redox kinetics. Structural and electronic analyses show unsaturated Mo sites act as Lewis acid centers for rapid, selective polysulfide conversion. In situ transmission electron microscopy with newly developed Na\u2010ion diffusion descriptors visualize ultrafast nanoscale sodiation dynamics and quantify Na\u2010ion transport. Consequently, the S@U\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    \/C cathode delivers an impressive capacity of 933 mAh g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    after 150 cycles at 200\u00a0mA g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    and retains 425 mAh g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    after 30\u00a0000 cycles at 10 A g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    . This work provides a mechanistic blueprint for designing high\u2010rate, long\u2010life Na\u2500S batteries by coupling catalysis with structural confinement.\n                  <\/jats:p>","DOI":"10.1002\/adma.72912","type":"journal-article","created":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T10:03:19Z","timestamp":1774519399000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Undercoordinated Molybdenum Catalysts Enable Ultrafast Quasi\u2010Solid Sulfur Chemistry in Sodium\u2010Sulfur Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Mingyue","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Energy Materials Science University of Shanghai for Science and Technology  Shanghai China"},{"name":"Institute for Superconducting and Electronic Materials Faculty of Engineering and Information Sciences University of Wollongong  North Wollongong New South Wales 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