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However, their practical deployment has been hindered by a low dimensionless figure of merit (ZT) and the reliance on high performance on complex processing routes. Here, we introduce a simple and controllable solvent\u2010assisted soft lithography approach for fabricating polymeric nanowires with exceptional thermoelectric performance. 1D confinement drives ordered chain assembly, boosting charge mobility (\n                    <jats:italic>\u00b5<\/jats:italic>\n                    ), while enhanced phonon\u2010boundary scattering suppresses lattice thermal conductivity (\n                    <jats:italic>\u03ba<\/jats:italic>\n                    <jats:sub>L<\/jats:sub>\n                    ). Compared with spin\u2010coated films, the nanowires achieve a 274% increase in\n                    <jats:italic>\u00b5<\/jats:italic>\n                    and a 63% reduction in\n                    <jats:italic>\u03ba<\/jats:italic>\n                    <jats:sub>L<\/jats:sub>\n                    , culminating in a peak ZT of 1.02 at 353 K. This nanowire\u2010based strategy is broadly applicable to diverse polymers, providing a robust route to nanostructure\u2010engineered plastic thermoelectrics with both high performance and scalable manufacturability, and opening new opportunities for practical organic thermoelectric devices.\n                  <\/jats:p>","DOI":"10.1002\/adma.73071","type":"journal-article","created":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T07:43:27Z","timestamp":1776152607000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Confined Assembly of Polymer Nanowires for High\u2010Performance Organic Thermoelectrics"],"prefix":"10.1002","volume":"38","author":[{"given":"Lixin","family":"Niu","sequence":"first","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"School of Chemical Sciences 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