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Bulk Ru crystallizes in the hexagonal close\u2010packed (\n                    <jats:italic>hcp<\/jats:italic>\n                    ) phase, but colloidal methods have enabled the synthesis of Ru nanocrystals in the metastable face\u2010centered cubic (\n                    <jats:italic>fcc<\/jats:italic>\n                    ) phase. In this report, we highlight recent progress in engineering the phase of Ru nanocrystals, with a focus on methods based on the seed\u2010templating effect, such as facet symmetry matching, and kinetic control over the reduction pathway. We also discuss the thermal stability of metastable\n                    <jats:italic>fcc<\/jats:italic>\n                    \u2010Ru nanocrystals, as well as their catalytic applications. We further summarize how\n                    <jats:italic>hcp<\/jats:italic>\n                    \u2010Ru nanocrystals can serve as templates to direct the synthesis of Pd and Rh nanocrystals in the metastable\n                    <jats:italic>hcp<\/jats:italic>\n                    phase. Finally, we offer perspectives on quantitative kinetic control, scalable synthesis, and stabilization of nanocrystals in metastable phases.\n                  <\/jats:p>","DOI":"10.1002\/adma.73072","type":"journal-article","created":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T07:48:51Z","timestamp":1776152931000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Recent Progress in the Phase\u2010Controlled Synthesis of Ruthenium Nanocrystals for Catalytic Applications"],"prefix":"10.1002","author":[{"given":"Jianlong","family":"He","sequence":"first","affiliation":[{"name":"School of Chemistry and Biochemistry Georgia Institute of Technology  Atlanta Georgia USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqi","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry Georgia Institute of Technology  Atlanta Georgia USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Guan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry Georgia Institute of Technology  Atlanta Georgia USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2431-7048","authenticated-orcid":false,"given":"Younan","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry Georgia Institute of Technology  Atlanta Georgia USA"},{"name":"The Wallace H. Coulter Department of Biomedical Engineering Georgia Institute of Technology and Emory University  Atlanta Georgia USA"},{"name":"Department of Materials Science and Engineering Johns Hopkins University  Baltimore Maryland USA"},{"name":"Department of Biomedical Engineering Johns Hopkins University  Baltimore Maryland 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