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Here, we design a new Co\u2010based metal\u2010organic framework (PKU\u201024) with a six\u2010coordinate structure that induces strong electron localization and suppresses the redox activity of Co sites, thereby blocking the electron\u2010transfer pathway. Interestingly, electron\u2010rich pollutants with oriented dipole moments can act as molecular \u201cswitches\u201d, effectively turning on PKU\u201024 activity for peroxymonosulfate (PMS) activation. Computations reveal that the dipole moment of pollutants is the decisive descriptor governing the behavior of organic contaminants in activating inert Co centers and reopening the electron\u2010transfer channel to mediate SO\n                    <jats:sub>5<\/jats:sub>\n                    <jats:sup>\u2022\u2212<\/jats:sup>\n                    toward selective singlet oxygen generation. Additionally, this work develops a large\u2010scale synthesis method for PKU\u201024 with a single synthesis yield of \u223c0.55\u00a0kg (costing \u223c0.52 USD g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and achieves long\u2010term, efficient, continuous treatment of organic wastewater. This work introduces a new principle for the design of pollutant\u2010sensitive Fenton\u2010like catalysts to achieve effective organic elimination while significantly reducing peroxide consumption.\n                  <\/jats:p>","DOI":"10.1002\/adma.73103","type":"journal-article","created":{"date-parts":[[2026,4,20]],"date-time":"2026-04-20T05:38:17Z","timestamp":1776663497000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Inert Catalytic Sites Unlocked by Micropollutants for Rapid Water Decontamination with Near\u2010Complete Chemical Utilization"],"prefix":"10.1002","volume":"38","author":[{"given":"Yu\u2010Hang","family":"Li","sequence":"first","affiliation":[{"name":"Eco\u2010environment and Resource Efficiency Research Laboratory, School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyi","family":"Liu","sequence":"additional","affiliation":[{"name":"Eco\u2010environment and Resource Efficiency Research Laboratory, School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanhao","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Pittsburgh  Pennsylvania USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaran","family":"Bai","sequence":"additional","affiliation":[{"name":"Eco\u2010environment and Resource Efficiency Research Laboratory, School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9635-5807","authenticated-orcid":false,"given":"Xiaoguang","family":"Duan","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Adelaide University  Adelaide South Australia Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haodong","family":"Ji","sequence":"additional","affiliation":[{"name":"Eco\u2010environment and Resource Efficiency Research Laboratory, School of Environment and Energy Peking University Shenzhen Graduate School  Shenzhen Guangdong P. R. 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