{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T10:52:37Z","timestamp":1789555957954,"version":"build-2803163510"},"reference-count":86,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T00:00:00Z","timestamp":1777334400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T00:00:00Z","timestamp":1777334400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20251"],"award-info":[{"award-number":["U22A20251"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52573236"],"award-info":[{"award-number":["52573236"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52572328"],"award-info":[{"award-number":["52572328"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Developing molecular sieves is vital, energy\u2010saving, but very challenging for gas separations in the petrochemical industry. Current molecular sieves reported for inverse CO\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    separation are very scarce and suffer from low CO\n                    <jats:sub>2<\/jats:sub>\n                    capacity and poor diffusion within the restricted nanopores. Herein, we report an electrostatically driven size\u2010sieving of CO\n                    <jats:sub>2<\/jats:sub>\n                    from C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    in a porous cation\u2010gated molecular sieve (Na\u2010RHO) with high CO\n                    <jats:sub>2<\/jats:sub>\n                    capacity and fast diffusion. Na\u2010RHO features large pore cavities (10.7 \u00c5) interconnected by small Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010gated pore windows (3.4 \u00c5), in which the Na\n                    <jats:sup>+<\/jats:sup>\n                    \u2010gated pore windows enable a complete size\u2010exclusion of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    due to the electrostatically driven sieving effect, and large pore cavities provide enough pore spaces to take up large amount of CO\n                    <jats:sub>2<\/jats:sub>\n                    with fast diffusion. Such an electrostatically driven molecular\u2010sieving mechanism for Na\u2010RHO was studied by gas sorption isotherms and theoretical calculations, leading to both the record\u2010high CO\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    selectivity (3.35\u00a0\u00d7\u00a010\n                    <jats:sup>6<\/jats:sup>\n                    ) and CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake capacity (188.0 cm\n                    <jats:sup>3<\/jats:sup>\n                    cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    ) at ambient conditions. Breakthrough experiments show that Na\u2010RHO can directly separate CO\n                    <jats:sub>2<\/jats:sub>\n                    impurity from CO\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    mixtures, with the highest dynamic selectivity (70.4) and C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    productivity (150.6 L kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) by far. This work provides a new strategy for designing more efficient molecular sieves with high gas capacity and diffusion for gas separations.\n                  <\/jats:p>","DOI":"10.1002\/adma.73196","type":"journal-article","created":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T06:22:05Z","timestamp":1777443725000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Electrostatically Driven Size\u2010Sieving of Carbon Dioxide From Acetylene Enabled by a Cation\u2010Gated Molecular Sieve"],"prefix":"10.1002","volume":"38","author":[{"given":"Yi\u2010Hong","family":"Yu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi\u2010Zhan","family":"Hao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Wen","family":"Gu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou China"},{"name":"ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui\u2010Min","family":"Wen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion College of Chemical Engineering Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7774-5452","authenticated-orcid":false,"given":"Bin","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guodong","family":"Qian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,28]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218274"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400276u"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/532435a"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2016.34"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz8881"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00756C"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00153C"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00418"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00328"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cbe.3c00115"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215093"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac064"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aay8447"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aao0092"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06397"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.4c00336"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ady2607"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309108"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adh0135"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat0586"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01784"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10620"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202210415"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016225"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c14895"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302882"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201027929\u20107"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18209"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013965"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514488"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03850"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03442"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102810"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00232"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015861"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05650"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11260"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00612"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07191"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00805"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500161"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300638"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106263"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201908275"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013988"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506055"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211523"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417183"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101907"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06138"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10491"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA05869J"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016673"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107906"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400823"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106769"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201039319\u20102"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202100584"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105880"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20210237"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209121"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218854"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201020489\u20102"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208756"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105491"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03265"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01705"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311419"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305390"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202419091"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202522386"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501870"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057972\u20107"},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/d5sc03281d"},{"key":"e_1_2_7_76_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05539"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja309274y"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063537\u20105"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00619C"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064823\u2010y"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116850"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1560"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15777"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06230"},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3070864"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm404028f"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01016"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.73196","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.73196","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.73196","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T07:14:34Z","timestamp":1782976474000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.73196"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,28]]},"references-count":86,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2026,6]]}},"alternative-id":["10.1002\/adma.73196"],"URL":"https:\/\/doi.org\/10.1002\/adma.73196","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,28]]},"assertion":[{"value":"2026-02-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e73196"}}