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However, its efficiency is fundamentally constrained by the piezoelectric screening effect, whereby accumulated free carriers rapidly neutralize polarization\u2010induced charges, leading to short\u2010lived internal fields and suppressed redox activity. Herein, ZnO nanoparticles are electrostatically integrated with a Zr\u2010based metal\u2013organic layer to construct a ZnO\/Zr\u2010MOL Z\u2010scheme heterojunction that intrinsically mitigates this screening limitation. Interfacial coupling enables polarization\u2010regulated band bending, spatially separating piezo\u2010generated electrons and holes, and preventing their premature compensation by mobile carriers. The Z\u2010scheme configuration preserves strong redox potentials while suppressing bulk and interfacial recombination, and the polarization\u2010driven charge redistribution and dynamic realignment of the conduction and valence bands sustain the piezoelectric potential and markedly enhance carrier mobility and lifetime. Consequently, the optimized ZnO\/Zr\u2010MOL catalyst achieves an H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production rate of 13.21\u00a0m\n                    <jats:sc>m<\/jats:sc>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in pure water under ambient air conditions. When incorporated into an autonomous tidal\u2010driven reactor, the heterostructure demonstrates strong environmental adaptability, achieving 74.5% degradation of Rhodamine B in 5 L of wastewater within 180\u00a0min. This study provides a fundamental strategy to overcome piezoelectric screening and establishes a mechanistic framework for polarization\u2010assisted charge transfer in heterostructure systems.\n                  <\/jats:p>","DOI":"10.1002\/adma.73242","type":"journal-article","created":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T06:47:03Z","timestamp":1777531623000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Suppressing Charge Screening via Z\u2010Scheme With Polarization Field for In Situ H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    Generation and Utilization"],"prefix":"10.1002","volume":"38","author":[{"given":"Cheng","family":"Chen","sequence":"first","affiliation":[{"name":"Key Laboratory of Integrated Regulation and Resource Development On Shallow Lakes, Ministry of Education College of Environment Hohai University  Nanjing 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