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Herein, we report a rational design strategy for robust, on\u2010demand debondable, and fully recyclable adhesives via constructing covalent adaptable ionic networks (CAINs). Integrating the advantages of poly(ionic liquid)s (PILs) and covalent adaptable networks (CANs), the CAINs exhibit exceptional adhesion strength (&gt;15\u00a0MPa on stainless steel), significantly outperforming most reported adhesives based solely on PILs or CANs. The material also maintains a shear strength of 11.0\u00a0MPa after immersion in liquid nitrogen, demonstrating excellent low\u2011temperature tolerance. Bis(trifluoromethanesulfonyl)imide anions endow the adhesives with remarkable hydrophobicity and excellent waterproof performance. Importantly, facile on\u2010demand debonding is achieved via ethanol treatment under mild conditions, enabling complete substrate separation and efficient material recovery with minimal performance degradation over multiple cycles. Mechanistic studies indicate that the covalent crosslinked network is the primary contributor to high adhesion, while hydrogen bonding plays a secondary supportive role. This work establishes a versatile platform for designing high\u2010performance dismantlable adhesives with superior recyclability, advancing sustainable adhesive technologies in advanced manufacturing and materials engineering.<\/jats:p>","DOI":"10.1002\/adma.73259","type":"journal-article","created":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T12:55:58Z","timestamp":1777553758000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Covalent Adaptable Ionic Networks for Robust, On\u2010Demand Dismantlable and Fully Recyclable Adhesives"],"prefix":"10.1002","volume":"38","author":[{"given":"Yang","family":"Ding","sequence":"first","affiliation":[{"name":"Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Suzhou Key Laboratory of Soft Material and New Energy College of Chemistry Chemical Engineering and Materials Science Soochow 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