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However, most systems rely on complex architectures or multi\u2010component triggers, limiting integration and responsiveness. Here, we develop a structurally homogeneous nanocluster\u2013gel platform by embedding water\u2010soluble gold nanoclusters (AuNCs) into a polyacrylamide matrix, enabling synchronized mechanical deformation and tunable luminescence in response to solvent polarity. Upon exposure to organic solvents, the gel rapidly contracts (&lt;5 s), while spatial confinement of AuNCs within the polymer boosts quantum yield from 6.05% to 22.83%. The emission profile is programmable by varying cluster size, highlighting AuNCs as structurally tunable emission modulators. Kinetic analysis reveals non\u2010Fickian swelling\/deswelling\u2014governed by solvent diffusion and polymer relaxation\u2014that synergistically modulates emission. This enables real\u2010time, quantitative optical detection of solvent gradients (R\n                    <jats:sup>2<\/jats:sup>\n                    = 0.996) with &gt;97% reversibility over 10 cycles. The integrated responsiveness is demonstrated in a biomimetic lotus\u2010shaped gel that folds and dims upon water uptake, and is further validated in a leakage scenario where the hydrogel serves as a pipe encapsulation film, achieving rapid sealing and visual monitoring of solvent leakage. This work establishes a nanocluster\u2013gel platform that unifies photophysics and actuation for adaptive, self\u2010indicating soft systems.\n                  <\/jats:p>","DOI":"10.1002\/adma.73386","type":"journal-article","created":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T15:01:50Z","timestamp":1778770910000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synchronizing Tunable Luminescence and Shape Morphing in a Metal Nanocluster\u2013Enabled Hydrogel Platform"],"prefix":"10.1002","volume":"38","author":[{"given":"Hongbin","family":"Lin","sequence":"first","affiliation":[{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate School (SIGS) Tsinghua University  Shenzhen China"},{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zening","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Gastric Surgery Fujian Medical University Union Hospital  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongshi","family":"He","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory For Analytical Science of Food Safety and Biology and State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongda","family":"Wei","sequence":"additional","affiliation":[{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate School (SIGS) Tsinghua University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhucheng","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Hu","sequence":"additional","affiliation":[{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate School (SIGS) Tsinghua University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhou","sequence":"additional","affiliation":[{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate School (SIGS) Tsinghua University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5484-0978","authenticated-orcid":false,"given":"Xiaorong","family":"Song","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory For Analytical Science of Food Safety and Biology and State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7414-7193","authenticated-orcid":false,"given":"Sanyang","family":"Han","sequence":"additional","affiliation":[{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate School (SIGS) Tsinghua University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3254-5799","authenticated-orcid":false,"given":"Jianping","family":"Xie","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 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