{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:09:36Z","timestamp":1784304576123,"version":"3.55.0"},"reference-count":54,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Paired electrolysis of CO\n                    <jats:sub>2<\/jats:sub>\n                    and biomass\u2010derived alcohols, such as 5\u2011hydroxymethylfurfural\u00a0(HMF) and glycerol, offers a sustainable approach for co\u2010producing valuable chemicals, but suffers from poor cathode\u2010anode compatibility and limited economic feasibility. Herein, we show that replacing CO\n                    <jats:sub>2<\/jats:sub>\n                    with carbon monoxide (CO) and adopting a catholyte\u2010layer electrolyzer design jointly enhance the operational stability of alcohol\u2010paired electrolysis by preventing HCO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    formation and suppressing inter\u2011electrode mass exchange. Within this platform, HMF oxidation is identified as the optimal anodic partner compared with glycerol oxidation, because it exhibits negligible product crossover and the oxidation kinetics of its intermediates consistently outpace those of the oxygen evolution reaction. Consequently, the paired electrolysis of CO and HMF in a membrane\u2010electrode assembly electrolyzer incorporating a catholyte\u2010layer enabled efficient and stable co\u2011production of ethylene and 2,5\u2011furandicarboxylic acid (FDCA), both key plastic monomers derived from CO\n                    <jats:sub>2<\/jats:sub>\n                    and biomass, respectively. Techno\u2010economic and environmental assessment indicate that the CO\u2010HMF pairing outperforms all tested combination of CO\n                    <jats:sub>2<\/jats:sub>\n                    or CO\u2010HMF or glycerol and approaches the production cost and carbon emission to petroleum\u2010derived terephthalic acid. These results demonstrate CO electrolysis coupled with HMF oxidation as a cost\u2010effective and climate\u2010conscious strategy for sustainable chemical production.\n                  <\/jats:p>","DOI":"10.1002\/adma.73411","type":"journal-article","created":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T08:40:59Z","timestamp":1779180059000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Economic Low\u2010Carbon Chemical Production via Paired Electrolysis of Carbon Monoxide (CO) and 5\u2010hydroxymethylfurfural (HMF)"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1323-7691","authenticated-orcid":false,"given":"Mi\u2010Young","family":"Lee","sequence":"first","affiliation":[{"name":"Clean Energy Research Center Korea Institute of Science and Technology  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8734-5826","authenticated-orcid":false,"given":"Dongjin","family":"Kim","sequence":"additional","affiliation":[{"name":"Clean Energy Research Center Korea Institute of Science and Technology  Seoul Republic of Korea"},{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-6835-8604","authenticated-orcid":false,"given":"Jun Woo","family":"Park","sequence":"additional","affiliation":[{"name":"Clean Energy Research Center Korea Institute of Science and Technology  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Geunsu","family":"Bae","sequence":"additional","affiliation":[{"name":"Department of Chemistry Pohang University of Science and Technology  Pohang Republic of 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