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Herein, we report HOF\u2010BUT\u20101, constructed from an unprecedented 8\u2010connected linker, resulting in compartmentalized porosity. This HOF thus combines high porosity (pore volume\u00a0=\u00a00.95\u00a0cm\n                    <jats:sup>3<\/jats:sup>\n                    \/g) with a small largest cavity diameter of 7.6\u00a0\u00c5. Enabled by its balanced pore structure, HOF\u2010BUT\u20101 exhibits a record\u2010high propylene uptake of 8.83\u00a0mmol\/g at 298\u00a0K and 1\u00a0bar, and thereby the highest separation potential (\u0394\n                    <jats:italic>Q<\/jats:italic>\n                    ) of 6.45\u00a0mmol\/g for equimolar C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    mixture among reported HOFs. Dynamic breakthrough experiments can deliver polymer\u2010grade C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    (\u226599.95%) and C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    (\u226599.5%) with productivities of 4.79 and 2.88\u00a0mmol\/g, respectively, and maintain performance over repeated cycles, demonstrating high potential for methanol\u2010to\u2010olefins products upgrading.\n                  <\/jats:p>","DOI":"10.1002\/adma.73579","type":"journal-article","created":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T11:30:25Z","timestamp":1780313425000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Compartmentalized Porosity in a Hydrogen\u2010Bonded Organic Framework Enables High\u2010Capacity C\n                    <sub>3<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    \/C\n                    <sub>2<\/sub>\n                    H\n                    <sub>4<\/sub>\n                    Separation"],"prefix":"10.1002","volume":"38","author":[{"given":"Yan\u2010Long","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9318-8839","authenticated-orcid":false,"given":"Xin","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR 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