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Ti\n                    <jats:sub>2<\/jats:sub>\n                    Nb\n                    <jats:sub>10<\/jats:sub>\n                    O\n                    <jats:sub>29<\/jats:sub>\n                    with Wadsley\u2010Roth phase with more open crystal structure is considered a promising candidate. However, Ti\/Nb atoms prefer to form an ordered arrangement to maintain local charge balance, resulting insufficient Li\n                    <jats:sup>+<\/jats:sup>\n                    migration and suppressing high\u2010rate performance. Herein, defective Ti\n                    <jats:sub>2<\/jats:sub>\n                    Nb\n                    <jats:sub>10<\/jats:sub>\n                    O\n                    <jats:sub>29\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    anode with partial disordered Ti\/Nb arrangement is developed by employing an amorphous precursor combined with Joule thermal shock. The random dispersion of Ti and Nb within the amorphous precursor is maintained to a certain extent during ultra\u2010fast Joule thermal heating (\u2248500\u00b0C s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and quenching (\u2248250\u00b0C s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Compared to traditional Ti\n                    <jats:sub>2<\/jats:sub>\n                    Nb\n                    <jats:sub>10<\/jats:sub>\n                    O\n                    <jats:sub>29<\/jats:sub>\n                    , the Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion coefficient and electronic conductivity of Ti\/Nb\u2010disordered Ti\n                    <jats:sub>2<\/jats:sub>\n                    Nb\n                    <jats:sub>10<\/jats:sub>\n                    O\n                    <jats:sub>29\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    are enhanced by tenfold and four orders of magnitude, respectively. As the anode of lithium\u2010ion batteries, the optimal Ti\n                    <jats:sub>2<\/jats:sub>\n                    Nb\n                    <jats:sub>10<\/jats:sub>\n                    O\n                    <jats:sub>29\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    shows an ultra\u2010high capacity of 353 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and an excellent rate capability of 112 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 150 C, an ultra\u2010long cycling lifespan of 5000 cycles, and a wide operating temperature range from 80\u00b0C to \u201040\u00b0C. The performance leap caused by the disordered structure may provide new paradigm for battery materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.73607","type":"journal-article","created":{"date-parts":[[2026,6,10]],"date-time":"2026-06-10T14:17:48Z","timestamp":1781101068000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Partial Atomic Disordered Ti\n                    <sub>2<\/sub>\n                    Nb\n                    <sub>10<\/sub>\n                    O\n                    <sub>29<\/sub>\n                    <i>\n                      <sub>\u2010x<\/sub>\n                    <\/i>\n                    Induced by Joule Thermal Shock for Superior Lithium\u2010Ion Storage"],"prefix":"10.1002","volume":"38","author":[{"given":"Yuwei","family":"Zhao","sequence":"first","affiliation":[{"name":"Key Laboratory of Intelligent Creation for Extreme Energy Materials of the Ministry of Education School 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