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Simultaneous yet decoupled monitoring of thermal and sweating\u2010related signals is therefore essential for reliable physiological assessment under intense motion. Here, we report a flexible, wireless, and fully passive dual\u2010mode sensing platform that enables independent detection of\u00a0sweat accumulation\u00a0and skin temperature on a single LC resonant architecture. The system integrates a sweat\u2010responsive electrochemical module and a thermosensitive conductive composite, both inductively coupled to a flexible serpentine coil for battery\u2010free near\u2010field interrogation.\u00a0We establish an orthogonal \u201cfrequency\u2013magnitude\u201d decoding strategy:\u00a0sweat\u2010induced dielectric changes dominantly drive resonance frequency shifts, while temperature\u2010dependent resistive losses primarily modulate the reflection coefficient magnitude (\n                    <jats:italic>\n                      S\n                      <jats:sub>11<\/jats:sub>\n                    <\/jats:italic>\n                    \u200b).\u00a0To further enhance robustness against signal coupling and motion artifacts, a machine\u2010learning\u2010assisted spectral decoder is introduced, enabling high\u2010accuracy recognition of joint physiological states.\u00a0Owing to its lightweight, maintenance\u2010free operation, and robust performance under vigorous motion, this platform provides a promising strategy for heat\u2010stress assessment and real\u2010time physiological monitoring in demanding scenarios such as military training and competitive sports.\n                  <\/jats:p>","DOI":"10.1002\/adma.73620","type":"journal-article","created":{"date-parts":[[2026,6,5]],"date-time":"2026-06-05T10:57:38Z","timestamp":1780657058000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Flexible Wireless Passive Platform for Decoupled Electrolyte and Temperature Sensing Toward Heat\u2011Stress Assessment"],"prefix":"10.1002","volume":"38","author":[{"given":"Yixuan","family":"Wang","sequence":"first","affiliation":[{"name":"School of Integrated Circuits and Electronics Beijing Institute of Technology  Beijing China"},{"name":"Institute of Flexible Electronics Beijing Institute of Technology  Beijing 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