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Here, an all\u2010solid\u2010state covalent organic framework electrolyte with sectionalized chemical environments (SCE\u2010COF) is reported, constructed via nanoconfined copolymerization of a highly dielectric monomer within COF nanochannels. The resulting architecture affords a nano\u2010confined molecular interface that integrates electron\u2010rich polar short chains that form abundant Li\n                    <jats:sup>+<\/jats:sup>\n                    hopping sites with electron\u2010deficient pore\u2010wall regions that immobilize anions through specific hydrogen\u2010bonding interactions, thereby enabling efficient and differential ion transport decoupled from strongly bonded solvation cage and polymer segmental motion. Benefiting from these synergistic effects, SCE\u2010COF achieves ionic conductivity of 1.05 \u00d7 10\n                    <jats:sup>\u22123<\/jats:sup>\n                    \u00a0S\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 30\u00b0C, a high Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number of 0.73 and a wide electrochemical window (4.87\u00a0V vs Li\n                    <jats:sup>+<\/jats:sup>\n                    \/Li). Finally, all\u2010solid\u2010state full cells employing SCE\u2010COF deliver a high specific energy density of 442.0\u00a0Wh\u00a0kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    under a controlled lithium source at ambient temperature.\n                  <\/jats:p>","DOI":"10.1002\/adma.73670","type":"journal-article","created":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T10:22:33Z","timestamp":1781000553000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Ion\u2010Selective Transport via Nanoconfined Differential Interfacial Friction in a Dielectric\u2010Engineered Covalent Organic Framework With Sectionalized Chemical Environments"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3773-7981","authenticated-orcid":false,"given":"Qi","family":"Zhang","sequence":"first","affiliation":[{"name":"Guangzhou Key Laboratory of Low\u2010Dimensional 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