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To address this issue, a robust bio\u2010interface based on an ultralight polyimide aerogel that combines high vapor permeability (1700\u00a0g\u00a0m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    \u00a0day\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    ) with intrinsic hydrophobicity (&gt;123\u00b0) is developed. Leveraging the superior thermal stability (up to 460\u00b0C), a liquid metal particle ink encapsulated by polyamic acid shell is activated through mild thermal treatment at 140\u00b0C. The resulting imidization\u2010induced contraction generates compressive stress to rupture insulating oxide layers and achieve a high electrical conductivity of 8.17 \u00d7 10\n                    <jats:sup>5<\/jats:sup>\n                    \u00a0S\u00a0m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    . This architecture employs an isotropic open\u2010cell framework that confines the ink to the surface while maintaining interconnected three\u2010dimensional (3D) pathways for lateral gas transport, thereby ensuring sustained breathability regardless of conductive layer coverage. Strong interfacial bonding through chemical coordination and mechanical interlocking enables negligible resistance variation over 200\u00a0000 deformation cycles and reliable underwater functionality. These synergistic advantages support diverse applications including conformal Joule heating, magnetic field sensing, and high\u2010fidelity electrophysiological monitoring during intense motion, establishing a versatile platform for next\u2010generation wearable healthcare.\n                  <\/jats:p>","DOI":"10.1002\/adma.73751","type":"journal-article","created":{"date-parts":[[2026,6,17]],"date-time":"2026-06-17T11:20:48Z","timestamp":1781695248000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["All\u2010Polyimide\u2010Mediated Liquid Metal Assembly on Aerogels for Breathable and Robust Electronic Skins"],"prefix":"10.1002","volume":"38","author":[{"given":"Haijun","family":"Zhu","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids School of Chemical and Material Engineering Ministry of Education Jiangnan University  Wuxi 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