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However, organic semiconductors generally suffer from inferior crystallinity and high lattice's susceptibility to molecular vibrations, which leads to the localization of separated charge carriers and severe recombination in nanoparticles, limiting the further improvement of photocatalytic H\n                    <jats:sub>2<\/jats:sub>\n                    evolution rate. Herein, a methoxy\u2010functionalized electron acceptor, ITIC\u2010OMe, is developed and presents enhanced crystallinity, more compact molecular packing and weaker electron\u2013phonon coupling, compared to the parent ITIC. This enables ZnTPP\u20103O:ITIC\u2010OMe bulk\u2010heterojunction nanoparticles to afford more ordered molecular stacking, reduced charge transfer resistance, and inhibited charge back transfer for triplet state formation, thereby suppressing charge carrier recombination and facilitating charge transport to the nanoparticle surface for proton reduction. Consequently, the photocatalyst based on ZnTPP\u20103O:ITIC\u2010OMe bulk\u2010heterojunction nanoparticles achieves an impressive hydrogen evolution rate up to 1017.7\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under AM 1.5G illumination, which is the record for organic photocatalysts so far. It highlights that suppressing charge carrier recombination via finely molecular design is a powerful route to enhance the photocatalytic H\n                    <jats:sub>2<\/jats:sub>\n                    evolution performance.\n                  <\/jats:p>","DOI":"10.1002\/adma.73857","type":"journal-article","created":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T15:47:02Z","timestamp":1782748022000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Suppressing Charge Carrier Recombination in Bulk Heterojunction Organic Photocatalyst via Improving Molecular Crystallinity and Reducing Electron\u2010Phonon Coupling for Efficient Hydrogen Evolution Reaction"],"prefix":"10.1002","volume":"38","author":[{"given":"Huixiang","family":"Sheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Powder Metallurgy College of Chemistry and Chemical Engineering Central South University  Changsha P. R. 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