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Here, we report a \u201cmortise\u2010and\u2010tenon\u201d strategy using a tulip\u2010shaped covalent organic framework (Tu\u2010COF) precursor to construct heteronuclear Ru\u2010Ln dual\u2010atom catalysts (Ln = La, Ce, Pr). The pre\u2010organized micropores of Tu\u2010COF serve as atomic\u2010scale nanoreactors, enabling precise confinement and pairing of Ru and lanthanide atoms. Among them, Ru\u2010Ce delivers outstanding CER performance, achieving 150\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 1.45\u00a0V versus RHE with nearly 100% Faradaic efficiency for Cl\n                    <jats:sub>2<\/jats:sub>\n                    evolution and over 500\u00a0h stability in a flow cell. Mechanistic studies identify the in situ formed RuCeCl\u2010N\n                    <jats:sub>6<\/jats:sub>\n                    motif as the active site. Density functional theory calculations reveal that adjacent Ce modulates the Ru center's d\u2010band structure and charge distribution, enhancing initial Cl adsorption on RuCe\u2010N\n                    <jats:sub>6<\/jats:sub>\n                    while optimizing subsequent Cl adsorption on RuCeCl\u2010N\n                    <jats:sub>6<\/jats:sub>\n                    . This lowers the free\u2010energy barrier for Cl\u2013Cl coupling and suppresses competing OOH\n                    <jats:sup>*<\/jats:sup>\n                    formation, thereby accelerating CER kinetics and intrinsically improving activity and selectivity. This work offers a generalizable strategy for heteronuclear DAC construction and highlights lanthanide\u2010mediated electronic engineering as a powerful approach to electrocatalyst design.\n                  <\/jats:p>","DOI":"10.1002\/adma.73881","type":"journal-article","created":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T13:28:45Z","timestamp":1782826125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Lanthanide\u2010Bridged Dual\u2010Atom Catalysts for Efficient Chlorine Electrosynthesis"],"prefix":"10.1002","volume":"38","author":[{"given":"Wen\u2010Da","family":"Zhang","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids School of Chemical and Material Engineering Ministry of Education Jiangnan University  Wuxi P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-5559-3882","authenticated-orcid":false,"given":"Han","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Zurich  Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids School of Chemical and Material Engineering Ministry of Education Jiangnan University  Wuxi P. R. 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