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However, smart membranes are locked by formidable trade\u2010off between permeance and selectivity during stimuli\u2010responsive process, owing to their synchronous, homogeneous stimuli\u2010responsive changes in channels. Here, we discover a new kind of smart membranes, hydrogel\u2010woven covalent organic framework (HW\u2010COF) membranes with orthogonal, opposite thermoresponsive nanochannels, overcoming the permeance\u2010selectivity trade\u2010off for achieving extraordinary aqueous separation. The key of HW\u2010COF membranes lies in the photothermal\u2010driven in\u2010situ confined weaving of poly(\n                    <jats:italic>N<\/jats:italic>\n                    \u2010isopropylacrylamide) hydrogel networks within orthogonal in\u2010plane pores and interlayer channels of two\u2010dimensional COF membranes for yielding mechanical interlocking architecture. Distinct from the non\u2010interlocked counterpart, HW\u2010COF membranes showcase a positive response in in\u2010plane pores yet a negative response in interlayer channels. This unique thermoresponsive behavior can be tailored by the synergy of in\u2010plane pores and interlayer channels, allowing HW\u2010COF membranes to obtain markedly positive response in both permeance and selectivity, almost not achievable with reported smart membranes. As a concept of demonstration, HW\u2010COF membranes can be applied for sieving water isotopologue\u00a0with ultrahigh selectivity (90.9%) and permeance (16.6 L m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    bar\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) using low\u2010grade heat as stimuli.\n                  <\/jats:p>","DOI":"10.1002\/adma.73948","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T11:55:56Z","timestamp":1784116556000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hydrogel\u2010Woven COF Membranes With Orthogonal, Opposite Thermoresponsive Nanochannels: Overcoming the Permeance\u2010Selectivity Trade\u2010off"],"prefix":"10.1002","volume":"38","author":[{"given":"Shuhui","family":"Ma","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao\u2010Nan","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuang\u2010Wei","family":"Gu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng\u2010Ye","family":"Zhu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang\u2010Chang","family":"Xu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingxiu","family":"Lv","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Zhang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced Organic Materials and Technologies Department of Polymer Science and Engineering Zhejiang University  Hangzhou China"},{"name":"The \u201cBelt and Road\u201d Sino\u2010Portugal Joint Lab on Advanced Materials International Research Center For X Polymers Zhejiang University  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Kang","family":"Xu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang Key Laboratory of Advanced 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