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The tunability of\n                    <jats:sup>19<\/jats:sup>\n                    F spin systems renders fluorinated materials versatile platforms for diverse applications. Although frequency encoding of\n                    <jats:sup>19<\/jats:sup>\n                    F nuclei enables high\u2010density molecular encoding, the use of spin relaxation remains limited. Here, a\n                    <jats:sup>19<\/jats:sup>\n                    F magnetic resonance display platform that exploits spin relaxation modulation through synergistic material\u2010level design and instrument\u2010level pulse sequence control is presented. Incorporation of paramagnetic metal ions into fluorinated deep eutectic solvents enables precise tuning of\n                    <jats:sup>19<\/jats:sup>\n                    F relaxation times for information encoding. Tailored relaxation\u2010selective pulse sequences allow selective visualization of the encoded information. Iron\u2010containing fluorinated deep eutectic solvents further enable reversible data editing via photoredox responses. In addition, UV\u2010printable paramagnetic fluorinated ionogels allow rapid and rewritable information display. This work expands nuclear magnetic information encoding by introducing controllable\n                    <jats:sup>19<\/jats:sup>\n                    F spin relaxation as an additional information domain, thereby converting spin relaxation from a physical parameter into an information carrier and enabling a selective, responsive, and non\u2010luminescent display platform well suited for high\u2010confidential anticounterfeiting and information display.\n                  <\/jats:p>","DOI":"10.1002\/adma.73987","type":"journal-article","created":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T07:54:21Z","timestamp":1783756461000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nuclear Spin Relaxation Modulation of Fluorinated Deep Eutectic Solvents for Radiofrequency Information Encoding and Display"],"prefix":"10.1002","volume":"38","author":[{"given":"Yuhang","family":"Jiang","sequence":"first","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Wang","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenlei","family":"Tan","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lexue","family":"Lin","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifan","family":"Li","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5675-8537","authenticated-orcid":false,"given":"Hongyu","family":"Lin","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhao","family":"Gao","sequence":"additional","affiliation":[{"name":"The MOE Key Laboratory of Spectrochemical Analysis &amp; Instrumentation, The Key Laboratory For Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering Xiamen University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,11]]},"reference":[{"key":"e_1_2_7_2_1","volume-title":"Introduction to Quantum Mechanics","author":"Schroeter D. 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