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In particular, acetone is an industrially important solvent and chemical feedstock, and its direct synthesis from CO\n                    <jats:sub>2<\/jats:sub>\n                    via photocatalysis represents a sustainable alternative to fossil\u2010based routes. Herein, we report chiral CuO\/HgS heterojunction photocatalysts for additive\u2010free photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to acetone. Chiral CuO and HgS were synthesized using chiral molecules as symmetry\u2010directing agents and subsequently assembled into heterojunctions with controlled handedness combinations. Structural and spectroscopic analyses confirm the successful construction of chiral interfaces. Photocatalytic tests reveal that the heterojunction catalysts exhibit significantly enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion efficiency and acetone selectivity compared to single components. The optimized system delivers improved charge separation efficiency, increased photocurrent response, and prolonged carrier lifetimes. This work demonstrates an effective heterojunction design strategy for promoting C\n                    <jats:sub>3<\/jats:sub>\n                    product formation from CO\n                    <jats:sub>2<\/jats:sub>\n                    and provides a sustainable approach for green acetone synthesis.\n                  <\/jats:p>","DOI":"10.1002\/adma.74014","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T18:13:37Z","timestamp":1785867217000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction to Acetone by Chiral HgS\/CuO Heterojunctions"],"prefix":"10.1002","volume":"38","author":[{"given":"Xuelong","family":"Bi","sequence":"first","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Frontiers Science Center For 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