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However, the low load\u2010bearing capacity of single 2D material and the unclear synergistic superlubricity mechanism severely constrain the design of long\u2010lasting superlubricity systems. Herein, through innovatively introducing van der Waals interaction\u2010induced molybdenum carbide\/molybdenum disulfide (Mo\n                    <jats:sub>2<\/jats:sub>\n                    CT\n                    <jats:sub>x<\/jats:sub>\n                    \/MoS\n                    <jats:sub>2<\/jats:sub>\n                    ) heterojunction as additives in ethylene glycol (EG), this Mo\n                    <jats:sub>2<\/jats:sub>\n                    CT\n                    <jats:sub>x<\/jats:sub>\n                    \/MoS\n                    <jats:sub>2<\/jats:sub>\n                    \u2013EG superlubricity system exhibits an ultralow friction coefficient of 0.0044, an extremely low wear rate of 8.17 \u00d7 10\n                    <jats:sup>\u221210<\/jats:sup>\n                    mm\n                    <jats:sup>3<\/jats:sup>\n                    \u2022N\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2022m\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and an ultralong lubrication life of 432\u00a0000 cycles (equal to 2160 m). Meanwhile, the maximum average contact pressure reaches 711.9\u00a0MPa. The in\u2010situ formed special tribofilms enriched with heterojunction and homojunction nanosheets effectively reduce the shear strength under boundary lubrication. Notably, the ultralow shear strength at the Mo\n                    <jats:sub>2<\/jats:sub>\n                    C\u2010O\/EG solid\u2013liquid interface and the unique pressure\u2010responsive lubrication properties of EG molecules which leads to the formation of short\u2010range\u2010ordered structures are also crucial for achieving superlubricity. This study provides a new perspective for designing novel solid\u2013liquid synergistic superlubricity systems by utilizing heterojunction nanomaterial and has great potential for application in industrial lubrication.\n                  <\/jats:p>","DOI":"10.1002\/adma.74061","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T08:24:42Z","timestamp":1784276682000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Macro\u2010Superlubricity Induced by Synergistic Effect of Molybdenum Carbide\/Molybdenum Disulfide Heterojunction and Conformation\u2010Transformable Ethylene Glycol Molecule"],"prefix":"10.1002","volume":"38","author":[{"given":"Xiaoyang","family":"Ma","sequence":"first","affiliation":[{"name":"State Key Laboratory of Tribology in Advanced Equipment Tsinghua University  Beijing 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