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Currently, no mechanism exists to reconcile the conflicting requirements of structural stability and rapid ion transport for high\u2010capacity silicon (Si) anodes: expansion\u2010accommodated encapsulation strategies preserve integrity but block interparticle ionic contact, while intrinsic electrochemical sintering restores conduction but creates excessive agglomeration that fractures the electrode. Here, we propose a stress\u2010lensed electrochemical sintering (SLES) strategy to guide selective interfacial bonding by depositing Si conformally into a porous carbon host, specifically utilizing its high\u2010curvature pore entrances as geometric constrictions. During cycling, these constrictions act as \u201cstress lenses\u201d, concentrating the volumetric expansion stress of Si precisely at interparticle contacts. This focused mechanical energy locally lowers the atomic diffusion barrier, guiding the formation of a robust, percolating Si network while preserving internal voids to buffer volume changes. The resulting Si\u2010SLES anode resolves the stability\u2010transport conflict, achieving \u223c100% capacity retention after 100 cycles with superior rate capability and demonstrating practical viability in full cells over 700 cycles.<\/jats:p>","DOI":"10.1002\/adma.74090","type":"journal-article","created":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T06:37:33Z","timestamp":1783924653000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Stress\u2010Lensed Electrochemical Sintering Enables Fast and Stable Lithium\u2010Silicon Alloy Chemistry in All\u2010Solid\u2010State Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Tianze","family":"Xu","sequence":"first","affiliation":[{"name":"Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, National Industry\u2010Education Integration Platform of Energy Storage, 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of Chemical Science and Engineering Tianjin University  Tianjin China"},{"name":"State Key Laboratory of Chemical Engineering and Low\u2010Carbon Technology Tianjin University  Tianjin China"},{"name":"Haihe Laboratory of Sustainable Chemical Transformations  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangbing","family":"Li","sequence":"additional","affiliation":[{"name":"Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, National Industry\u2010Education Integration Platform of Energy Storage, and Collaborative Innovation Center of Chemical Science and Engineering Tianjin University  Tianjin China"},{"name":"State Key Laboratory of Chemical Engineering and Low\u2010Carbon Technology Tianjin University  Tianjin China"},{"name":"Haihe Laboratory of Sustainable Chemical Transformations  Tianjin 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