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Simultaneously achieving high luminescence and charge transport properties of nonfullerene acceptors (NFAs) remains a major challenge due to the complex, nonlinear relationship between molecular structure and solid\u2010state packing. In this study, we demonstrate a molecular design concept based on the \u201cbutterfly effect\u201d that enables precise control over intermolecular packing in A\u2013DA\u2032D\u2013A\u2010type NFAs through subtle substituent modifications on the remote phenyl ring. Systematic modulation with methoxy, methyl, hydrogen, and fluorine groups reveals distinct packing configurations: methoxy\u2010substituted AQxPO enhances photoluminescence quantum yield (PLQY to 9.96%) via depressed end\u2013bridge (E\u2013B) stacking but disrupts vital charge transport pathways, while fluorine\u2010substituted AQxPF promotes E\u2013B\/end\u2013end (E\u2013E) stacking, enhancing carrier transport at the cost of reduced PLQY (4.78%). Notably, the hydrogen\u2010substituted AQxPH optimally suppressing detrimental E\u2013B stacking while maintaining efficient E\u2013E interactions, yielding both high PLQY and superior charge transport. Consequently, the D18:AQxPH\u2010based binary OSC achieves a remarkable PCE of 20.9% with a high V\n                    <jats:sub>OC<\/jats:sub>\n                    of 0.925\u00a0V at an ultralow non\u2010radiative energy loss of 0.176\u00a0eV. This work provides a design principle to overcome OSC efficiency bottlenecks through precise stacking control.\n                  <\/jats:p>","DOI":"10.1002\/adma.74119","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T08:38:57Z","timestamp":1784104737000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Remote Modification\u2010Induced Butterfly Effect on Nonfullerene Acceptor Aggregation for Efficient Organic Solar Cells"],"prefix":"10.1002","volume":"38","author":[{"given":"Renjie","family":"Xu","sequence":"first","affiliation":[{"name":"Center For Future Organic Optoelectronics Global Institute of Future Technology (GIFT) Shanghai Jiao Tong University  Shanghai P. R. China"},{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of Sciences  Beijing P. R. 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