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Ultrafast heating and cooling can kinetically trap immiscible elements into solid solutions, expanding the compositional space and optimizing the properties of high\u2010entropy materials. However, the extreme temperatures required by these non\u2010equilibrium methods are incompatible with metal\u2013organic frameworks (MOFs). This work presents a flame aerosol strategy for synthesizing compositionally complex, entropically stabilized MOFs, enabling new combinations of properties previously inaccessible in this class of materials. Using the HKUST structure as a prototype, this methodology is extended to a wide array of both crystalline and amorphous MOFs, and then to a 10\u2010element MOF that incorporates transition metals, rare\u2010earth metals, alkaline\u2010earth metals, p\u2010block metals, and noble metals. This strategy can be further applied to inorganic coordination polymers. This study reveals that kinetics and entropy collectively drive structural short\u2010range periodicity and configurational disorder in the framework, which in turn influence crystallinity, pore architecture, defect density, homogeneity, and electrochemical properties. This work expands the compositional design space for MOFs and offers new opportunities for their fundamental study and practical application.<\/jats:p>","DOI":"10.1002\/adma.74201","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T07:07:14Z","timestamp":1784790434000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Non\u2010Equilibrium Flame Aerosol Process to Create High\u2010Entropy MOFs"],"prefix":"10.1002","volume":"38","author":[{"given":"Shuo","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemical and Biological Engineering University At Buffalo The State University of New York  Buffalo New York USA"},{"name":"The Molecular Foundry Lawrence Berkeley National Laboratory  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiashun","family":"Liang","sequence":"additional","affiliation":[{"name":"Department of 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