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However, high\u2010performance three\u2010terminal artificial synapses based on these materials remain scarce due to challenges in forming high\u2010quality semiconductor films. Here, we demonstrate a perovskite synaptic field\u2010effect transistor (FET) capable of efficient 940\u00a0nm sensing and neuromorphic modulation, enabled by uniform, high\u2010crystallinity FASn\n                    <jats:sub>0.8<\/jats:sub>\n                    Pb\n                    <jats:sub>0.2<\/jats:sub>\n                    I\n                    <jats:sub>3<\/jats:sub>\n                    thin films. A molecular additive, 1\u2010bromo\u20104\u2010(methylsulfinyl)benzene (BMSB), precisely regulates crystallization, enlarges grains, and suppresses trap formation, thereby reducing ion migration and enhancing charge transport. The optimized devices achieve high hole mobility and an exceptional responsivity of 231\u00a0A W\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 940\u00a0nm, marking the first demonstration of efficient 940\u00a0nm infrared photoresponse in three\u2010terminal perovskite artificial synapses. Benefiting from balanced ion\u2010electron coupling, the devices exhibit reliable synaptic behaviors, including excitatory postsynaptic currents, paired\u2010pulse facilitation, and learning\u2013forgetting cycles. Integrated into a reservoir\u2013computing framework, the synaptic FETs enable accurate NIR facial recognition, underscoring their potential for in\u2010sensor computing. This work establishes a molecular\u2010level strategy to harmonize ionic and electronic processes in Sn\u2500Pb perovskites, advancing light\u2010programmable neuromorphic transistors for next\u2010generation intelligent NIR vision systems.\n                  <\/jats:p>","DOI":"10.1002\/adma.74226","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T08:30:03Z","timestamp":1784536203000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["940\u00a0Nm Near\u2010Infrared Photosynapses Based on Sn\u2500Pb Perovskite for Efficient Face Recognition"],"prefix":"10.1002","volume":"38","author":[{"given":"Wanqi","family":"Duan","sequence":"first","affiliation":[{"name":"Key Laboratory of Pulp and Paper Science &amp; Technology of Ministry of Education and State Key Laboratory of Green Papermaking and Resource Recycling Qilu University of Technology (Shandong Academy of Sciences)  Jinan 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