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Here, we report a defect anchoring strategy that selectively exploits sulfur\u2010defect\u2010rich interfacial sites as chemically specific docking sites for Pt\u2013S coordination, enabling stable Pt deployment at an ultralow loading of only 0.084 wt%. In situ spectroscopy and first\u2010principles calculations reveal that these defect\u2010anchored Pt\u2013S motifs efficiently extract electrons from interfacial sulfur sites and optimize hydrogen adsorption thermodynamics for accelerated HER kinetics. The optimized photocatalyst delivers hydrogen evolution rates of 22.43\u2009mmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under visible light and 91.35\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under full\u2010spectrum irradiation, exhibiting excellent long\u2010term stability. When immobilized as a scalable catalyst film via an immersion process, it achieves an areal H\n                    <jats:sub>2<\/jats:sub>\n                    flux of 331.34\u00a0mmol m\n                    <jats:sup>\u22122<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . More broadly, we show that the same defect\u2010guided Pt\u2010anchoring rule operates across multiple ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    \u2010based heterojunctions, highlighting a transferable site\u2010definition strategy for atom\u2010economical noble\u2010metal deployment. Ultimately, this approach redefines interfacial defects in heterojunction photocatalysts as programmable chemical sockets for noble\u2010metal placement, establishing a general blueprint for atom\u2010economical and scalable solar hydrogen generation.\n                  <\/jats:p>","DOI":"10.1002\/adma.74254","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T08:26:26Z","timestamp":1784795186000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Selective Pt\u2013S Anchoring at Interfacial Defects for Atom\u2010Economical Solar Hydrogen Production"],"prefix":"10.1002","volume":"38","author":[{"given":"Chiyao","family":"Zheng","sequence":"first","affiliation":[{"name":"School of Physical Science and Technology, Jiangsu Key Laboratory of Frontier Material Physics and Devices, Suzhou Key Laboratory of Intelligent Photoelectric Perception, Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Center For Energy Conversion Materials &amp; Physics (CECMP) Soochow University  Suzhou P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4655-8619","authenticated-orcid":false,"given":"Shumin","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology, Jiangsu Key Laboratory of Frontier Material Physics and Devices, Suzhou Key Laboratory of Intelligent Photoelectric Perception, Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Center For Energy Conversion Materials &amp; Physics (CECMP) Soochow University  Suzhou P. R. 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