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While atomic Ru\u2013O active sites hold great promise for the CER, they are severely hindered by instability and strong OH* poisoning. Herein, we report an interlayer\u2010engineered electrode where a MnO\n                    <jats:sub>2<\/jats:sub>\n                    nano\u2010interlayer epitaxially wraps a nanocone array to confine and modulate atomic Ru\u2013O clusters. This interlayer induces strong electronic coupling via Ru\u2012O\u2012Mn\u2012O\u2012Ti linkages that spatially confine and anchor the clusters to suppress dissolution while triggering substantial interfacial electron redistribution. Crucially, this modulated electronic environment effectively promotes optimizes *Cl adsorption, thereby significantly enhancing intrinsic CER selectivity and kinetics. Consequently, the electrode achieves exceptional durability over 1200\u00a0h with negligible Ru dissolution. When integrated into a proton\u2010exchange\u2010membrane electrolyzer, the catalyst demonstrates superior activity and stability, benefiting from the hierarchical architecture that facilitates superaerophobic bubble release and enhanced mass transport. These findings establish a generalizable strategy unifying atomic confinement, electronic modulation, and transport engineering for designing durable CER electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/adma.74344","type":"journal-article","created":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T06:45:16Z","timestamp":1785307516000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Integrated Multiscale Nanoarrays With MnO\n                    <sub>2<\/sub>\n                    \u2010Mediated Ru\u2500O Clusters for Stable Acidic Chlorine Evolution"],"prefix":"10.1002","volume":"38","author":[{"given":"Chaoyang","family":"Sun","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing Key Laboratory of Intelligent Design and Manufacturing for Hydrogen Energy Materials Beijing University of Chemical Technology  Beijing 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