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However, compared to other metal clusters, actinide clusters are still underexplored, especially high\u2010nuclearity thorium clusters. Here, we developed a synthetic strategy, in the form of \u201ccluster from cluster\u201d to construct the highest nuclearity thorium cluster (\n                    <jats:bold>\n                      Th\n                      <jats:sub>38<\/jats:sub>\n                    <\/jats:bold>\n                    ) so far. It exhibits remarkable stability under high \u03b3\u2010ray irradiation (up to 690 kGy) and displays unprecedented dispersibility and stability under strong acid conditions (pH = 1). Moreover, the high stability and unique electronic structure of\n                    <jats:bold>\n                      Th\n                      <jats:sub>38<\/jats:sub>\n                    <\/jats:bold>\n                    renders it an excellent catalyst for the photocatalytic synthesis of 4\u2010quinazolinones. This work utilizes a strategy to achieve the selfassembly of the highest nuclearity\n                    <jats:bold>\n                      Th\n                      <jats:sub>38<\/jats:sub>\n                    <\/jats:bold>\n                    and expands its potential applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.74375","type":"journal-article","created":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T10:16:08Z","timestamp":1785406568000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Controlled Synthesis of High\u2010Nuclearity Th\n                    <sub>38<\/sub>\n                    Cluster for Efficient Photocatalytic Dehydrogenative Cross\u2010Coupling"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-1374-7047","authenticated-orcid":false,"given":"Qian","family":"Niu","sequence":"first","affiliation":[{"name":"School of Chemistry South China 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