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While the magnetism of kagome materials has been widely investigated, their unconventional superconductivity (SC) remains largely unexplored due to the limited availability of suitable materials. Here, we report evidence of unconventional SC in the  family by combining muon\u2010spin spectroscopy measurements with band\u2010structure calculations. The parent  undergoes a structural phase transition from a high\u2010 cubic\u2010 to a low\u2010 rhombohedral phase, while the Ir kagome layer remains, albeit slightly, distorted. Although the structural transition is suppressed by Si substitution, the superconducting pairing of  remains well described by a two\u2010gap model. Since at least one of the gaps exhibits nodes, this indicates an unconventional SC. Its unconventional nature can be explained by the distinct flat bands occurring near the Fermi level, leading to strong electronic correlations in the  family. Moreover, the low\u2010 phase of  exhibits an Ir chiral chain; therefore, it can be classified as a topological chiral crystal. Overall, the unusual properties of the  family make it an interesting, albeit rare, system for studying the interplay between unconventional SC, flat bands, and chirality.<\/jats:p>","DOI":"10.1002\/adma.74399","type":"journal-article","created":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T06:05:44Z","timestamp":1785996344000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unconventional Superconductivity in ScIr\n                    <sub>2<\/sub>\n                    Chiral Crystal With a Kagome Lattice"],"prefix":"10.1002","volume":"38","author":[{"given":"Keqi","family":"Xia","sequence":"first","affiliation":[{"name":"School of Physics East China Normal University Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhou","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Physics School of Science, Tianjin University Tianjin 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