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However, its rapid film formation results in a narrow processing window and severely limits industrial scalability. Therefore, reducing solvent selectivity during active\u2010layer processing is essential to facilitate scalable OSC manufacturing. Herein, this critical issue is finely addressed by a solid\u2010additive\u2010assisted strategy, in which 2,6\u2010dimethylnaphthalene (2,6\u2010DMN) is incorporated to modulate the film formation dynamic and molecular aggregation in different processing solvents. It is revealed that 2,6\u2010DMN enables stage\u2010specific control over the film formation process. Its mechanism involves suppressing acceptor aggregation during spin\u2010coating and then promoting ordered acceptor self\u2010assembly during annealing. This two\u2010stage modulation simplifies donor\u2013acceptor interactions, mitigates excessive aggregation caused by slow solvent drying, and thereby prevents large\u2010scale phase separation. As a result, 2,6\u2010DMN induces a highly uniform and favorable active\u2010layer morphology across various processing solvents, thereby alleviating performance variations\u00a0in devices caused by solvent effect. Consequently, the 2,6\u2010DMN\u2010based PM6:D18:L8\u2010BO\u2010X ternary device processed from\n                    <jats:italic>o<\/jats:italic>\n                    \u2010xylene achieves a remarkable efficiency of 20.86%, setting a record for non\u2010halogenated solvent\u2010processed OSCs. This work provides a practical and efficient solid\u2010additive\u2010assisted strategy to mitigate the solvent selectivity in OSCs, demonstrating significant potential for achieving high\u2010performance OSCs with enhanced processing compatibility.\n                  <\/jats:p>","DOI":"10.1002\/adma.74452","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T18:17:12Z","timestamp":1785867432000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Reducing Solvent Selectivity via Solid Additive\u2010Assisted Strategy Enables Organic Solar Cells With Approaching 21% Efficiency"],"prefix":"10.1002","volume":"38","author":[{"given":"Jiali","family":"Song","sequence":"first","affiliation":[{"name":"International Research Center For Carbon Neutralization State Key Laboratory of Bioinspired Interfacial Materials Science Hangzhou International Innovation Institute Beihang University  Hangzhou P. 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