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Here, we introduce a dynamic soft\u2010confinement strategy using bubble\u2010assisted assembly to manipulate molecular aggregation via tunable surface energy at the solid\u2010liquid interface. By controlling the morphologies of microfluidic channels (necktie\u2010like, strip\u2010like, and necklace\u2010like), we achieve distinct self\u2010assembled aggregates of microcubes, corded scaffolds, and microplates, with tailored freedom of the photoswitchable molecule. The strip\u2010like channel, formed by thinning bubble walls, traps metastable intermediates, yielding a corded scaffold structure with favorable light penetration, weaker intermolecular interactions, and loosened molecular packing for isomerization. This design achieves near\u2010quantitative bidirectional\n                    <jats:italic>E<\/jats:italic>\n                    \u21c6\n                    <jats:italic>Z<\/jats:italic>\n                    photoisomerization (96%\u201398%) in the solid\u2010state, rivaling solution\u2010like performance. Multi\u2010scale characterization and computational analyses reveal the critical role of confined aggregation kinetics in controlling molecular motion. Furthermore, heterogeneous patterning demonstrates programmable photoresponsive arrays for photomechanical applications. This strategy provides a scalable platform for dynamically controlling supramolecular self\u2010assembly pathways and designing solid\u2010state photoresponsive materials with programmable functions.\n                  <\/jats:p>","DOI":"10.1002\/adma.74453","type":"journal-article","created":{"date-parts":[[2026,8,9]],"date-time":"2026-08-09T09:51:02Z","timestamp":1786269062000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Bubble\u2010Assisted Dynamic Confinement Enables Programmable Solid\u2010State Photoswitching and Heterogeneous Photoresponsive Architectures"],"prefix":"10.1002","volume":"38","author":[{"given":"Mengmeng","family":"Guo","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Science CAS Key Laboratory of Green Printing Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"University of Chinese Academy of Sciences  Beijing 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