{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T15:57:41Z","timestamp":1791475061864,"version":"4.3.4"},"reference-count":48,"publisher":"Wiley","issue":"56","license":[{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T00:00:00Z","timestamp":1786320000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92372127"],"award-info":[{"award-number":["92372127"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22179066"],"award-info":[{"award-number":["22179066"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52336003"],"award-info":[{"award-number":["52336003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2023JQ017"],"award-info":[{"award-number":["ZR2023JQ017"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["202210060028"],"award-info":[{"award-number":["202210060028"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2021QE061"],"award-info":[{"award-number":["ZR2021QE061"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Ni\u2010rich layered oxides (LiNi\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Co\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    Mn\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sub>\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ,\n                    <jats:italic>x<\/jats:italic>\n                    \u2265 0.8) are indispensable for high\u2010energy\u2010density lithium\u2010ion batteries, yet they suffer from severe chemomechanical degradation driven by the synergy of internal microcracking and interfacial parasitic side reactions. Existing strategies inherently suffer from decoupled regulation of mechanical and chemical instabilities that fail to address these issues holistically. Here, we develop an inside\u2010out structural reconfiguration strategy driven by the thermal decomposition of nitrates, concurrently tailoring the core, bulk, and surface of NCM811 in a single calcination step. This reconstruction generates a stress\u2010buffering central pore architecture that effectively homogenizes anisotropic lattice strain and suppresses crack nucleation. Concurrently, the regulated Nd\n                    <jats:sup>3+<\/jats:sup>\n                    diffusion forms a coherent Nd\n                    <jats:sub>4<\/jats:sub>\n                    [LiNi]O\n                    <jats:sub>8<\/jats:sub>\n                    (NLNO) perovskite phase within the bulk lattice, creating a pinning effect that stabilizes the layered framework and enhances charge transport. Furthermore, excess Nd\u2010species evolve into a conformal NLNO surface coating, acting as a physical barrier and oxygen reservoir to resist electrolyte attack and oxygen evolution. The modified cathode delivers an exceptional capacity retention (95.7% after 200 cycles at 4.5\u00a0V) and exceptional rate capability (157.1 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 C). Even under stringent conditions (4.6\u00a0V or 45\u00b0C), a superior retention of 87.8% is maintained after 200 cycles, demonstrating remarkable chemomechanical robustness.\n                  <\/jats:p>","DOI":"10.1002\/adma.74572","type":"journal-article","created":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T08:06:31Z","timestamp":1786349191000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Holistic Inside\u2010Out Reconfiguration of Ni\u2010Rich Cathodes via a Thermally Self\u2010Driven Strategy for Exceptional Chemomechanical Stability"],"prefix":"10.1002","volume":"38","author":[{"given":"Haixia","family":"Yu","sequence":"first","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shucheng","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"},{"name":"Beijing Frontier Research Center on Clean Energy Institute of Physics Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyuan","family":"Song","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guihuan","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhonghan","family":"Song","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rizhen","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5498-5066","authenticated-orcid":false,"given":"Qinghao","family":"Li","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhou","sequence":"additional","affiliation":[{"name":"Instruments Center for Physical Science University of Science and Technology of China  Hefei Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongfu","family":"Tang","sequence":"additional","affiliation":[{"name":"Hebei Key Laboratory of Applied Chemistry School of Environmental and Chemical Engineering Yanshan University  Qinhuangdao Hebei China"},{"name":"Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and Technology Yanshan University  Qinhuangdao Hebei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"He","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8513-518X","authenticated-orcid":false,"given":"Xiqian","family":"Yu","sequence":"additional","affiliation":[{"name":"Beijing Frontier Research Center on Clean Energy Institute of Physics Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8891-260X","authenticated-orcid":false,"given":"Qiang","family":"Li","sequence":"additional","affiliation":[{"name":"College of Physics College of Materials Science and Engineering Weihai Innovation Research Institute Qingdao University  Qingdao China"},{"name":"Department of Electrical and Computer Engineering &amp; Institute for Quantum Computing University of Waterloo  Ontario Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,10]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202523158"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.72965"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2026.102400"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201800561"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201019991\u20104"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100107\u20102"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.70868"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302170"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301096"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201900985"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201900032"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045373\u20101"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054637\u20109"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b00122"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4ee01400f"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c18922"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010020\u20100767\u20108"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.7b00907"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c20005"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209483"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0cc01715a"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1088\/2515\u20107639\/abe392"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0ta08132a"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005238\u20103"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c01397"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201043792\u20100"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401052"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202419903"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12119"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202406175"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.72940"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003404"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma1004036834"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.05.054"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eti.2021.101825"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b01876"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.04.001"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c00279"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c11645"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207225"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c20868"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010025\u201001998\u2010x"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00566"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202406068"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.3c00565"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361\u2010648X\/ab7fd8"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201011299\u20102"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001402\u2010x"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74572","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.74572","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74572","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T15:29:10Z","timestamp":1791473350000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.74572"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,10]]},"references-count":48,"journal-issue":{"issue":"56","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/adma.74572"],"URL":"https:\/\/doi.org\/10.1002\/adma.74572","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,10]]},"assertion":[{"value":"2026-04-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74572"}}